Fe3O4@PDA@PANI core-shell nanocomposites as a new adsorbent for simultaneous preconcentration of Tartrazine and Sunset Yellow by ultrasonic-assisted dispersive micro solid-phase extraction

In this research, novel magnetic Fe3O4@PDA@PANI core-shell nanoparticles were designed and fabricated as an efficient adsorbent in the service of ultrasound-assisted dispersive micro-solid phase extraction for simultaneous preconcentration of Sunset Yellow (SY) and Tartrazine (Tar) before UV-Vis spectrophotometric detection. This adsorbent was fully characterized by Fourier Transform Infrared (FT-IR) spectroscopy, Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), and Energy Dispersive X-ray (EDX) analysis. To overcome the spectral overlapping of SY and Tar dyes, the derivative spectrophotometric method was successfully used for the simultaneous detection of dyes in their binary solutions. The operating parameters affecting preconcentration efficiency and spectrophotometric determination were optimized. Under optimal conditions, the limit of detections (LOD) was obtained 0.2 and 0.5 ng mL(-1) for SY and Tar, respectively. The adsorption capacity and reusability of core-shell nanoparticles were significant. The satisfactory results of analysis of a few real samples indicate that the method is very favored in the analysis of various complex matrices. (C) 2021 Elsevier B.V. All rights reserved.

Automated summary

Novel magnetic Fe3O4@PDA@PANI core-shell nanoparticles were designed and fabricated for efficient adsorption of Sunset Yellow (SY) and Tartrazine (Tar), with simultaneous detection achieved using derivative spectrophotometric method. Under optimized conditions, the detection limits for SY and Tar were 0.2 and 0.5 ng mL(-1) respectively. The core-shell nanoparticles showed significant adsorption capacity and reusability, making the method favored for analysis of complex matrices.