期刊
SEPARATION AND PURIFICATION TECHNOLOGY
卷 274, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.seppur.2021.119132
关键词
Adsorption; Metal-organic frameworks; Xe; Kr separation; Pore shapes
资金
- National Natural Science Foundation of China [21908090]
- Natural Science Foundation of Jiangxi Province [20192ACB21015]
This study reported two metal-organic frameworks for the adsorptive separation of xenon and krypton, with Al-CDC showing higher adsorption capacity and selectivity due to its narrow pore aperture and pore structure. The results indicate potential industrial applications and stable reusability of these materials.
Adsorptive separation of xenon (Xe) from krypton (Kr) is challenging owing to their low concentrations and similar physical properties. Herein, we report two metal-organic frameworks (MOFs) assembled from the same aliphatic ligand (trans-1, 4-cyclohexanedicarboxylic acid, H2CDC), but showing distinct pore shapes. The rhombus pores on Al-CDC show a narrower pore aperture of 4.5 & Aring; x 6.0 & Aring;, contracting to the pseudo-square pores (5.8 & Aring; x 6.8 & Aring;) on Cu-CDC. As a result, Al-CDC exhibits a high Xe adsorption capacity (2.45 mmol g-1) and Xe/Kr selectivity (10.7) at 298 K and 1.0 bar. The confined pore space and abundant saturated C-H groups provide stronger van der Waals interactions toward Xe, which is disclosed by the Grand Canonical Monte Carlo (GCMC) and Density Functional Theory (DFT) calculations. Dynamic breakthrough experiments further confirm their industrial application potential and stable reusability.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据