Activation of peroxymonosulfate by bimetallic CoMn oxides loaded on coal fly ash-derived SBA-15 for efficient degradation of Rhodamine B

In this study, we successfully synthesized SBA-15 mesoporous molecular sieve with coal fly ash (CFA) as the silicon source, fabricated bimetallic CoMn catalysts with the obtained SBA-15 as the support, and evaluated their performance for activating peroxymonosulfate (PMS) to degrade the Rhodamine B (RhB) in an aqueous solution. The characterization results signified that MnCo2O4 spinel was formed and uniformly dispersed on SBA-15 for the as-prepared CoMn/SBA-15. The CoMn/SBA-15/PMS system exhibited markedly higher RhB removal efficiency compared with Co/SBA-15/PMS and Mn/SBA-15/PMS under the same reaction conditions. Moreover, bimetallic CoMn/SBA-15 presented much lighter metal leaching than the monometallic catalysts. Chemical quenching tests and electron paramagnetic resonance experiments ascertained the generation of free radicals (SO4-center dot and (OH)-O-center dot) and non-radical (singlet oxygen, O-1(2)) reactive oxygen species by PMS activation and the dominant role O-1(2) in RhB degradation. The formed intermediate products by RhB degradation were identified with LC-MS analyses. We have also performed LC-MS analyses to determine the formed intermediate products during RhB degradation. The present results demonstrate the pronounced potential of CFA as a silicon source of molecular sieve support for preparing various heterogeneous catalysts for the PMS-based oxidation of organic pollutants in wastewater.

Automated summary

In this study, SBA-15 mesoporous molecular sieve was successfully synthesized using coal fly ash as the silicon source, bimetallic CoMn catalysts were fabricated, and their performance in degrading Rhodamine B in an aqueous solution was evaluated. The results showed that CoMn/SBA-15 had higher RhB removal efficiency and lower metal leaching compared to monometallic catalysts. The study demonstrated the potential of using coal fly ash as a silicon source for preparing heterogeneous catalysts for oxidative degradation of organic pollutants in wastewater.