期刊
SENSORS AND ACTUATORS B-CHEMICAL
卷 353, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2021.131087
关键词
NO2 gas sensing; UV activation; ZnO; Ti3C2Tx MXene; High surface area
资金
- National Natural Science Foundation of China [51802123, 62101225]
- Special project for international scientific and technological cooperation-Zhihui Yunnan plan [202103AM140040]
- Natural Science Foundation of Jiangsu Province [BK20180630]
The novel Ti3C2Tx MXene/ZnO nanorod hybrids demonstrated high response, sensing rate, sub-ppb detecting limit, reproducibility, and reversibility for optoelectronic NO2 sensors. By introducing mesostructured Ti3C2Tx MXene/ZnO nanorod hybrids, the sensor showed greatly enhanced optoelectronic and gas-sensing performance to ppb-leveled NO2 under UV illumination, with superior reversibility, sub-ppb detection limit, and high selectivity to NO2. The UV-activated NO2-sensing property was attributed to the hierarchical mesostructure and effective photogenerated carrier separation of Ti3C2Tx MXene, suggesting the promising application of MXene-metal oxide hybrids for high-performance UV-activated NO2 sensors at ambient temperature.
Here, a kind of novel Ti3C2Tx MXene/ZnO nanorod hybrids was reported for optoelectronic NO2 sensors with high response, high sensing rate, sub-ppb detecting limit and superior reproducibility and reversibility. A facile anchored growth method was developed to obtain mesostructured Ti3C2Tx MXene/ZnO nanorod hybrids with a surface area of 146.8 m(2)/g. The sensor based on MXene/ZnO nanorod hybrids demonstrated greatly enhanced optoelectmnic and gas-sensing performance to ppb-leveled NO2 upon UV illumination, in comparison with pure ZnO nanorods. The sensing responses to 5-200 ppb NO2 ranged from 21% to 346% at ambient temperatures, and the response time was 17 s and the recovery time was 24 s (to 50 ppb NO2). Moreover, the mesoporous hybrids exhibited the features of superior reversibility, sub-ppb detection limit (down to 0.2 ppb) and high selectivity to NO2. The extraordinary UV-activated NO2-sensing property was ascribed to the hierarchical mesostructure in addition to the effective photocarrier separation rendered by the highly photoconductive Ti3C2Tx MXene. This work demonstrates that rationally designed MXene-metal oxide hybrid sensitive materials are promising candidates for high-performance UV-activated NO2 sensor operated at ambient temperature.
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