4.7 Article

One-pot electrodeposition of metal organic frameworks composite accelerated by gold nanoparticles and electroreduced carbon dots for electroanalysis of bisphenol A in real plastic samples

期刊

SENSORS AND ACTUATORS B-CHEMICAL
卷 346, 期 -, 页码 -

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.snb.2021.130499

关键词

Metal organic frameworks composite; Gold nanoparticles; Electroreduced carbon dots; One-Pot electrodeposition; Bisphenol A electroanalysis

资金

  1. National Natural Science Foundation of China [21305039]
  2. Natural Science Foundation of Hunan Prov-ince [2020JJ4346, 14JJ3097]
  3. Foundation of Department of Edu-cation of Hunan Province [20K063]
  4. Degree & Postgraduate Education Reform Project of Hunan Province [2019JGYB130]
  5. Hunan Natural Science Foundation for Distinguished Young Scholars [2021JJ10001]
  6. Hunan Science and Technology Talent Promotion Project [2020TJ-Q12]
  7. Provincial Innovation and Entrepreneurship Training Program for College Students [S201910537026]

向作者/读者索取更多资源

A sensitive electroanalysis method for bisphenol A (BPA) based on a novel metal organic frameworks (MOFs) composite was developed, using gold nanoparticles (AuNPs) and electroreduced carbon dots (ErCDs) to enhance the conductivity of the composite. The electrochemical sensor showed a wide linear range and a low detection limit for BPA, with satisfactory recovery when applied to test BPA in plastic products.
A sensitive electroanalysis of bisphenol A (BPA) based on a novel metal organic frameworks (MOFs) composite of MOFs, gold nanoparticles (AuNPs) and electroreduced carbon dots (ErCDs) was reported. The MOFs composite (AuNPs-ErCDs-MOFs) was in-situ prepared by one-pot electrodeposition approach. Scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), Fourier transform infrared spectrometer (FT-IR), cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and differential pulse voltammetry (DPV) were used to show the properties of the composite. Interestingly, AuNPs, ErCDs, and AuNPs-ErCDs are found to significantly accelerate electrodeposition of MOFs, and used as good conductive agent to enhance the conductivity of MOFs composite. The electrochemical sensor shows wide linear range from 7.0 x 10(-8) mol/L to 5 x 10(-7) mol/L and 5 x 10(-7) mol/L to 1.3 x 10(-6) mol/L for BPA with a detection limit of 32 nmol/L (S/N = 3). In addition, the proposed sensor was also applied to test the BPA in plastic products with satisfactory recovery.

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