Sustainable materials in the removal of pesticides from contaminated water: Perspective on macro to nanoscale cellulose

Recently, over utilization of pesticides in agrarian and non-agrarian sectors has resulted in a significant increment in the deposition of their remnants in different segments of the environmental media. The presence of pesticides and transportation of their different metabolites in rivers, ponds, lakes, soils, air, groundwater sources and drinkable water sources has demonstrated a high threat to human wellbeing and the climate. Thus, the removal of pesticides and their metabolites from contaminated water is imperative to lessen the ill effects of pesticides on human beings. In the present article, we have appraised recent advances in pesticides removal utilizing low cost pristine and functionalized cellulose biomass-based derivatives. One of the key focus has been on better understand the destiny of pesticides in the environment as well as their behaviour in the water. In addition, the impact of magnetite cellulose nanocomposites, cellulose derived photo nano-catalyst, cellulose/clay nano composites, CdS/cellulose nanocomposites and activated carbons/biochar on percent removal of pesticides have also been a part of the current review. The impact of different parameters such as adsorbent dosage, pH, time of contact and initials pesticide concentration on adsorption capacity and adsorption kinetics followed during absorption by different cellulosic bio-adsorbents has also been given. The cellulosic biomass is highly efficient in the removal of pesticides and their efficiency further increases upon functionalization or their conversion into activated carbons forms. Nano particles loaded cellulosic materials have in general found to be less efficient than raw, functionalized cellulosic materials and activated carbons. Further, among different nano particles loaded with cellulose-based materials, cellulose/MnO2 photonanocatalyst were noticed to be more effective. So considerable efforts should be given to determine the finest practices that relate to the dissipation of different pesticides from the water. (C) 2021 Published by Elsevier B.V.

Automated summary

The recent article evaluates the latest progress in pesticides removal using low-cost pristine and functionalized cellulose biomass-based derivatives, emphasizing on understanding the fate of pesticides in the environment and their behavior in water. Different parameters affecting adsorption capacity and kinetics of cellulosic bio-adsorbents have been assessed, highlighting the efficiency of cellulose biomass in removing pesticides.