☆ 4.7 Review

Frontiers in circularly polarized luminescence: molecular design, self-assembly, nanomaterials, and applications

SCIENCE CHINA-CHEMISTRY (2021)

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Article Engineering, Environmental

Highly strong luminescent chiral nematic cellulose nanocrystal/PEI composites for anticounterfeiting

Yuchen Jiang et al.

Summary: A matrix swelling and in-situ insertion method was developed to fabricate chiral nematic composite films with increased ultimate strain, toughness, and folding endurance. The intercalation of PEI into CNC films also resulted in fluorescence enhancement and circularly polarized luminescence properties, with controllable CPL handedness. The CNC composite films displayed optical responsiveness to various stimuli, making them promising for manufacturing foldable encryption materials.

CHEMICAL ENGINEERING JOURNAL (2022)

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Article Chemistry, Physical

A new strategy to achieve enhanced upconverted circularly polarized luminescence in chiral perovskite nanocrystals

Xue Jin et al.

Summary: This study presents a method for achieving circularly polarized luminescence activity using a hybrid nanomaterial of upconversion nanoparticles and perovskite nanocrystals. By embedding UCNPs into PKNCs, various CPL activities including prompt CPL, UC-CPL, and energy transfer enhanced CPL were realized. Chiral perovskite nanocrystals showed energy transfer enhanced CPL activity with four times magnification of the circular polarization.

NANO RESEARCH (2022)

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Review Chemistry, Multidisciplinary

Quantifying the Overall Efficiency of Circularly Polarized Emitters

Lorenzo Arrico et al.

Summary: This study introduces a new concept of CPL brightness (B-CPL), which takes into consideration the absorption extinction coefficient and quantum yield in addition to the g(lum) factor, to comprehensively evaluate the efficiency of CPL emitters. By calculating B-CPL values for over 180 compounds and analyzing the data distribution for main classes of CPL molecular emitters, this tool can aid in contextualizing new CPL active compounds and guiding the selection of molecular systems for specific CPL applications.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Article Chemistry, Multidisciplinary

Quinoline-based aggregation-induced delayed fluorescence materials for highly efficient non-doped organic light-emitting diodes

Liang Zhang et al.

Summary: Three new emitters with quinoline as a new electron acceptor were designed and synthesized, showing thermally activated delayed fluorescence (TADF) properties and aggregation-induced emission (ALE) feature. High-performance non-doped OLEDs based on these emitters achieved excellent maximum external quantum efficiencies (EQE(max)), indicating their promising application in OLEDs.

CHINESE CHEMICAL LETTERS (2021)

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Article Chemistry, Multidisciplinary

Real-Time Visual Monitoring of Kinetically Controlled Self-Assembly

Zizhao Huang et al.

Summary: This study monitored the self-assembly process of chiral DPAC derivatives in real time using vibration-induced emission, revealing distinct optical and morphological characteristics of different assemblies. Additionally, strong circularly polarized luminescence was induced during the morphology transformation process. The excited-state characteristics of the self-assemblies allowed effective investigation of the relationship between molecular aggregation and conformational change.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Assembly-Induced Strong Circularly Polarized Luminescence of Spirocyclic Chiral Silver(I) Clusters

Han Wu et al.

Summary: The study involved constructing spirocyclic Ag-9 clusters by vertex-sharing of in-situ-generated heteroaryl diide-centered metal rings, demonstrating versatile photoluminescent and chiroptical behavior. Under different aggregation conditions, assembly led to cluster-based phosphorous luminescence and micrometer-long helical nanofibers. Exciton couplings of chelating ligands at molecular and microscopic levels in the assembled film of cluster enantiomers resulted in circularly polarized luminescence with a high anisotropy factor (0.16).

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Dinuclear Triple-Stranded Helicates Composed of Tetradentate Ligands with Aluminum(III) Chromophores: Optical Resolution and Multi-color Circularly Polarized Luminescence Properties

Toshikazu Ono et al.

Summary: A new type of chiroptical chromophores composed of tetradentate ligands with aluminum(III) ions exhibit multi-color photoluminescence with quantum yields up to 54%. The right-handed and left-handed helicates are stable and do not racemize in some solvents, showing mirror images in circular dichroism and circularly polarized luminescence. Mixing different helicates can produce white light emission with CPL characteristics, providing potential applications for chromophores with diverse photophysical properties.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

500-Fold Amplification of Small Molecule Circularly Polarised Luminescence through Circularly Polarised FRET

Jessica Wade et al.

Summary: The study presents a method to achieve nearly 1000-fold chiroptical amplification by embedding a pi-extended superhelicene in an achiral conjugated polymer matrix. This approach significantly increases the chiroptical factor of the superhelicene in solid-state blend films, offering a simple and versatile way to enhance the g-factors of small organic molecules.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Enantiomeric Switching of the Circularly Polarized Luminescence Processes in a Hierarchical Biomimetic System by Film Tilting

Michidmaa Khorloo et al.

Summary: The research team demonstrated a crystalline chiral polymer film as a polarizing medium, using radially assembled twisted crystallites and confined AIEgens to achieve switchable CPL. This new material shows great optical performance and potential for a wide range of applications.

ACS NANO (2021)

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Article Chemistry, Multidisciplinary

Multi-Modal Chiral Superstructures in Self-Assembled Anthracene-Terminal Amino Acids with Predictable and Adjustable Chiroptical Activities and Color Evolution

Zhuoer Wang et al.

Summary: The study uncovers the universal existence of supramolecular tilt helical superstructures in self-assembled pi-conjugated amino acid derivatives, providing insights into the chiroptical phenomena and facilitating the rational design and fabrication of emerging chiroptical materials.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Circularly Polarized Luminescence from Solvent-Free Chiral Organic π-Liquids

Xue Bai et al.

Summary: The study reported naphthalene derivatives substituted with chiral branched alkyl chains, with circular dichroism (CD) and circularly polarized luminescence (CPL) only observed for enantiomeric Nap2 when in liquid form at room temperature.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Chiral Spiro-Axis Induced Blue Thermally Activated Delayed Fluorescence Material for Efficient Circularly Polarized OLEDs with Low Efficiency Roll-Off

Yi-Pin Zhang et al.

Summary: This study achieved efficient circularly polarized OLEDs by introducing a spiral-axis skeleton and TADF molecules, demonstrating high efficiency and low efficiency roll-off.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Adaptive Chirality of an Achiral Cucurbit[8]uril-Based Supramolecular Organic Framework for Chirality Induction in Water

Yawen Li et al.

Summary: Achiral supramolecular organic framework (SOF-1) can exhibit adaptive chirality induced by specific compounds in water, leading to mirror-image circular dichroism and circularly polarized luminescence. This adaptive chirality can be utilized for determining the enantiopurity of amino acids and distinguishing biological chiral macromolecules.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Improving the Overall Properties of Circularly Polarized Luminescent Materials Through Arene-Perfluoroarene Interactions

Haowen Zhang et al.

Summary: A supramolecular self-assembled system driven by arene-perfluoroarene (AP) interactions of chiral polycyclic aromatic hydrocarbons (PAHs) and octafluoronaphthalene (OFN) provides a solution to the trade-off in the field of circularly polarized luminescence (CPL) of pure organic materials, where the large luminescence dissymmetry factor usually suppresses luminescence efficiency. Chirality amplification in both excited and ground states, as well as enhanced luminescence efficiency compared with individual chiral PAHs, are achieved in the AP assemblies due to the energy-barrier effect of OFN, showing potential for developing highly efficient CPL-active materials.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Inorganic & Nuclear

Chiral gold(I)-containing polymeric composites: chiroptical sensing and circularly polarized luminescence

Pingxia Guo et al.

Summary: In this study, fiber-like gold(I)-containing polymeric composites were successfully constructed in water, showing gradual luminescence enhancement with increasing molecular weight of the PLGSm block. Chiral transfer was achieved for the first time, resulting in strong circularly polarized luminescence (CPL), providing a general approach for constructing CPL active polymer/metal complex composites.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2021)

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Article Chemistry, Physical

Ultrastrong Red Circularly Polarized Luminescence Promoted from Chiral Transfer and Intermolecular Forster Resonance Energy Transfer in Ternary Chiral Emissive Nematic Liquid Crystals

Kun Yao et al.

Summary: Chiral emissive liquid crystals (N*-LCs) have been shown to significantly enhance circularly polarized luminescence (CPL) signals due to a regular spiral arrangement of dyes. By doping AIE active donors and ME active acceptors into N-LCs, CPL-active ternary chiral emissive N-LCs (T-N*-LCs) are formed, which can emit strong red CPL through intermolecular energy transfer and chirality induction. This work provides an effective strategy for developing high g(lum) CPL materials.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2021)

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Article Chemistry, Multidisciplinary

Handedness-inverted polymorphic helical assembly and circularly polarized luminescence of chiral platinum complexes

Zhong-Liang Gong et al.

Summary: This research demonstrates the preparation of polymorphic helical architectures with highly efficient CPL and inverted handedness by controlling the assembly pathway of chiral emitters.

SCIENCE CHINA-CHEMISTRY (2021)

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Article Multidisciplinary Sciences

π-Extended perylene diimide double-heterohelicenes as ambipolar organic semiconductors for broadband circularly polarized light detection

Li Zhang et al.

Summary: In this study, a novel approach of skeleton merging was introduced to address the dilemma between strong coupling with circular polarized light and high charge-carrier mobility in high-performance chiral organic semiconducting molecules. The resulting pi-extended double helicene structure exhibits high dissymmetry factor, extended pi-planar system for charge transport properties, near-infrared light absorption, and ambipolar charge transport abilities, enabling high photoresponsivity and external quantum efficiency in both p- and n-type modes under NIR light irradiation. These characteristics allow for high-performance broadband CPL detections up to the NIR spectral region.

NATURE COMMUNICATIONS (2021)

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Article Materials Science, Multidisciplinary

Turn-On Circularly Polarized Luminescence in Metal-Organic Frameworks

Xue-Zhi Wang et al.

Summary: In this study, a family of homochiral metal-organic frameworks (MOFs) and metal-organic cages (MOCs) were constructed by solvothermal subcomponent self-assembly. The homochiral MOFs showed clear CPL signals, while the CPL of homochiral MOCs was silent. Despite having similar spectra of circular dichroism and photoluminescence, the CPL activity of MOFs and MOCs differed.

ADVANCED OPTICAL MATERIALS (2021)

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Article Nanoscience & Nanotechnology

Enhancing Optical Activities of Benzimidazole Derivatives through Coassembly for High-Efficiency Synthesis of Chiroptical Nanomaterials and Accurate ee % Detection of Natural Acids

Jianjian Zhao et al.

Summary: Efficient protocols were developed to enhance the optical activities of chiral self-assemblies, leading to improved chiroptical responses and accurate detection of enantiomeric excess. Coassembly with natural hydroxyl acids resulted in the formation of chiral nanostructures with enhanced chiral recognition and detection capabilities, showing increased dissymmetry g-factors.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Steering Nanohelix and Upconverted Circularly Polarized Luminescence by Using Completely Achiral Components

Minghao Zhou et al.

Summary: A general supramolecular coassembly approach was developed for fabricating upconverted circularly polarized luminescence systems from completely achiral components, inducing UC-CPL activity through the formation of a chiral nanohelix via symmetry breaking. The research demonstrated that chiral molecules are not required for the fabrication of UC-CPL materials, and the polarization of UC-CPL can be tuned by the helicity of the nanohelix.

ACS NANO (2021)

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Article Chemistry, Multidisciplinary

Direct Visualization of Chiral Amplification of Chiral Aggregation Induced Emission Molecules in Nematic Liquid Crystals

Qing Xia et al.

Summary: This study provides a systematic exploration of chiral amplification of chiral aggregation induced emission (AIE) molecules in liquid crystals (LCs) from direct visualization of their co-assemblies at the nano scale to theoretical calculation of the molecular packing modes on a single molecular level. The direct visualization using AFM imaging revealed that chiral AIE molecules self-assembled into helical fibers to serve as the helical template for LCs to bind, forming co-assemblies with morphologies of pearled necklaces or thick rods. Theoretical calculations suggested that chiral AIE molecules were packed into left-handed helical fibers with empty space between neighboring molecules, providing binding sites for LCs.

ACS NANO (2021)

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Review Chemistry, Multidisciplinary

Polarization-Sensitive Halide Perovskites for Polarized Luminescence and Detection: Recent Advances and Perspectives

Xiaobo Wang et al.

Summary: This paper comprehensively summarizes the research status and development direction in the field of polarization-sensitive HPs, introducing principles, methods, and strategies.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Bright Long-Lived Circularly Polarized Luminescence in Chiral Chromium(III) Complexes

Juan-Ramon Jimenez et al.

Summary: Chiral CrIII complexes with dual circularly polarized luminescence in the near-infrared region have been successfully synthesized, providing potential applications for quantifying chiral targets in biological systems.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

AIE-Active Chiral [3]Rotaxanes with Switchable Circularly Polarized Luminescence

Wei-Jian Li et al.

Summary: A new family of AIE-active chiral [3]rotaxanes were designed and synthesized, with a novel CPL switching system successfully constructed by controlling the motions of the chiral pillar[5]arene macrocycles along the axle through the addition or removal of acetate anions. This resulted in reversible transformations between two emission states with high PLQYs and g(lum) values.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Circularly Polarized Luminescence Liquids Based on Siloxybinaphthyls: Best Binaphthyl Dihedral Angle in the Excited State

Kazuto Takaishi et al.

Summary: A series of axially chiral 1,1'-binaphthyls with trialkylsiloxy (OSiR3) groups have been synthesized, with some showing circularly polarized luminescence (CPL) in liquid state at room temperature. Time-dependent DFT calculations revealed a transoid conformation in the excited state is essential for the CPL activity, with a dihedral angle of approximately 110 degrees.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Biased Symmetry Breaking and Chiral Control by Self-Replicating in Achiral Tetradentate Platinum (II) Complexes

Bo Yang et al.

Summary: This study presents a new method for achieving homochirality from achiral platinum (II) liquid crystals, showcasing the potential for chiral control through the use of homochiral liquid crystal films as templates. The self-assembled superhelix structures exhibit prominent circularly polarized luminescence in the twist grain boundary phase.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Spontaneous resolution and absolute chiral induction of 3d-4f heterometal-organic frameworks from achiral precursors

Manting Chen et al.

Summary: The study found that in the presence of lactic acid enantiomers, three-dimensional chiral 3d-4f heterometal-organic frameworks can be formed and spontaneously resolved from achiral ligands, while in the absence of lactic acid enantiomers, the reactants randomly generated both enantiopure crystals. The enantiopure lactic acid induced asymmetric resolution to achieve single chiral crystallization. DFT theoretical calculations showed that the absolute chiral resolution of the enantiomers is due to the difference in the interactions between the two enantiomeric units and the chiral inducer.

SCIENCE CHINA-CHEMISTRY (2021)

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Article Materials Science, Multidisciplinary

Efficient Circularly Polarized Electroluminescence from Chiral Thermally Activated Delayed Fluorescence Emitters Featuring Symmetrical and Rigid Coplanar Acceptors

Feng-Ming Xie et al.

Summary: This study reports two pairs of axially chiral emitting enantiomers with flexible and rigid structures, exhibiting thermally activated delayed fluorescence properties and obvious mirror-image circularly polarized luminescence characteristics. The CP-OLEDs based on these enantiomers demonstrate high efficiency and significant CPL effects.

ADVANCED OPTICAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Chiral Helical Polymer/Perovskite Hybrid Nanofibers with Intense Circularly Polarized Luminescence

Biao Zhao et al.

Summary: Chiral perovskites with circularly polarized luminescence (CPL) performance have attracted significant attention. A convenient and universal strategy for constructing chiral helical polymer/perovskite hybrid nanofibers with outstanding CPL properties has been reported in this contribution. The prepared hybrid nanofibers exhibit good long-time stability in air and intense CPL emissions, with the emission color easily tunable by adjusting the precursors of perovskites, providing an efficient technique for various kinds of CPL-active perovskite nanomaterials for both scientific research and future practical applications.

ACS NANO (2021)

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Article Chemistry, Multidisciplinary

Circularly Polarized Laser with Chiral Nematic Cellulose Nanocrystal Cavity

Dan Qu et al.

Summary: A method of fabricating circularly polarized lasers using cellulose nanocrystals and a laser dye through evaporation-induced assembly is presented, showing controlled chiral nematic structure and modification of laser polarization state into left-handed, resulting in strong and tailored CP laser emission.

ACS NANO (2021)

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Article Chemistry, Multidisciplinary

Stimulated Chiral Light-Matter Interactions in Biological Microlasers

Zhiyi Yuan et al.

Summary: This study introduces the concept of a biological chiral laser and amplifies chiral light-matter interactions in an active resonator through the stimulated emission process. The significant enhancement of chiral light-matter interactions was demonstrated due to the nonlinear pump energy dependence of stimulated emission. The findings elucidate the mechanism of stimulated chiral light-matter interactions, providing better understanding of light-matter interaction in biophysics, chiral sensing, and quantum biophotonics.

ACS NANO (2021)

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Review Chemistry, Multidisciplinary

Chiral Perovskites for Next-Generation Photonics: From Chirality Transfer to Chiroptical Activity

Sunihl Ma et al.

Summary: Organic-inorganic hybrid halide perovskites (OIHPs) are widely used in various applications due to their exceptional optoelectrical properties and structural flexibility. Despite intriguing chiral properties, the transfer mechanism from chiral molecules to achiral semiconductors and the origin of chiroptical activity are still not extensively studied. This comprehensive review discusses recent advances in chiroptical activities of chiral OIHPs and provides insight into the underlying chirality transfer mechanism.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Programmable Metal Nanoclusters with Atomic Precision

Yingwei Li et al.

Summary: Recent advances in atomically precise nanochemistry have allowed for programmable control over nanoparticle size and structure. Gold-thiolate nanoclusters exhibit strong quantum-confinement effects, with changes in the energy gap depending on the core structure.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Bamboo-like π-Nanotubes with Tunable Helicity and Circularly Polarized Luminescence

Yuan Wang et al.

Summary: A bamboo-like pi-nanotube was fabricated through the self-assembly of a dipeptide-substituted naphthalenediimide gelator, demonstrating tunable helicity and circularly polarized luminescence (CPL). The helicity and CPL of the nanotubes can be adjusted by the amount of trifluoroacetic acid (TFA), and the helicity can be conveyed to achiral quantum dots to produce materials with adjustable dissymmetry factor. This work reveals the control of helicity and CPL in a new type of self-assembled bamboo-like pi-nanotube.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Rational Design of Multicolor-Emitting Chiral Carbonized Polymer Dots for Full-Color and White Circularly Polarized Luminescence

Yi Ru et al.

Summary: This study reports the synthesis of red- and multicolor-emitting Ch-CPDs using common precursors and a solvothermal approach, achieving high quantum yield and circularly polarized luminescence. Additionally, circularly polarized white-emitting CPDs were fabricated for the first time by tuning the mixing ratio of colored Ch-CPDs in a gel, opening up exciting opportunities for designing functional chiroptical materials.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Full-Color and White Circularly Polarized Luminescence of Hydrogen-Bonded Ionic Organic Microcrystals

Zhong-Qiu Li et al.

Summary: This paper proposes a simple method for in situ preparation of circularly polarized luminescence (CPL)-active microcrystals, which achieves control of luminescence dissymmetry through hydrogen bonding interactions between molecules, allowing for tunable emission colors, ordered morphology, and high luminescence efficiency.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Chiral Hybrid Perovskite Single-Crystal Nanowire Arrays for High-Performance Circularly Polarized Light Detection

Zhen Liu et al.

Summary: A direct CPL detector with high photocurrent and polarization selectivity has been developed based on low-defect CHP single-crystal nanowire arrays, achieving a high light on/off ratio, excellent responsivity, and outstanding anisotropy factor for photocurrent. Large-scale CHP nanowires were obtained through a micropillar template-assisted capillary-bridge rise approach, providing useful insight for direct CPL detection in high-performance chiral optoelectronics.

ADVANCED SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Amplification of Dissymmetry Factors in π-Extended [7]- and [9]Helicenes

Zijie Qiu et al.

Summary: In this study, pi-Extended [7]helicene and pi-Extended [9]helicene were successfully synthesized with improved photophysical properties and high circularly polarized luminescence brightness. The research also revealed that a small variation in helical length can cause an increase in dissymmetry factors.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Alkynyl-Stabilized Superatomic Silver Clusters Showing Circularly Polarized Luminescence

Miao-Miao Zhang et al.

Summary: This study introduces a new enantiomeric pair of superatomic silver clusters, R/S-Ag-17, prepared from chiral alkynyl ligands, which exhibit near-infrared emission and circularly polarized luminescence. Experimental and theoretical evidence suggest that the CPL originates from transitions between superatomic 1P(z) and 1S orbitals. This work paves the way for the development of CPL-active metal nanoclusters utilizing chiral ligands and demonstrates the transfer of chirality from protecting ligands to superatomic states in metal clusters.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Polymer Science

Bottlebrush Polymers Carrying Side Chains on Every Backbone Atom: Controlled Synthesis, Polymerization-Induced Emission, and Circularly Polarized Luminescence

Wen-Bin Liu et al.

Summary: Controlled synthesis of bottlebrush polymers with high grafting density and carrying polymeric side chains on every backbone atom is a great challenge. In this study, well-defined polymers bearing polymerizable phenyl isocyanide were prepared, and polymerization of these macromonomers yielded bottlebrush polymers with PLLA or PDLA side chains on every backbone atom. The densely grafted polymers exhibited intriguing photoluminescence and induced clear circularly polarized luminescence with defined handedness.

MACROMOLECULES (2021)

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Article Chemistry, Multidisciplinary

Solvent-driven reversible transformation between electrically neutral thiolate protected Ag25 and Ag26 clusters

Yu-Ling Tan et al.

Summary: Two atom-precise silver nanoclusters, Ag-25 and Ag-26, were synthesized using the thiolate protective ligand Tab. The weak Ag-S interaction in Tab-protected clusters allows for reversible conversion through solvent-triggered core fragmentation and re-arrangement.

SCIENCE CHINA-CHEMISTRY (2021)

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Article Materials Science, Multidisciplinary

Light-Responsive Circularly Polarized Luminescence Polymers with INHIBIT Logic Function

Zizhao Huang et al.

Summary: This study synthesized light-responsive and luminescence-tunable CPL-active materials by mixing different polymers, and comprehensively investigated CPL-active materials with VIE properties for the first time. By regulating dynamic FRET to control the emission color of CPL, an INHIBIT logic gate was constructed based on the multi-stimuli responsive CPL signal in different states.

ADVANCED OPTICAL MATERIALS (2021)

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Review Optics

Circularly polarized luminescence from organic micro-/nano-structures

Yongjing Deng et al.

Summary: This article summarizes the recent progress of CPL from organic micro-/nano-structures, outlining the design principles and external stimuli that can regulate CPL performance. It introduces several typical organic micro-/nano-structures with CPL activity and summarizes their applications in organic light-emitting diodes, optical information processing, and chemical and biological sensing.

LIGHT-SCIENCE & APPLICATIONS (2021)

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Article Nanoscience & Nanotechnology

Planar Chiral [2.2]Paracyclophane-Based Thermally Activated Delayed Fluorescent Materials for Circularly Polarized Electroluminescence

Chen Liao et al.

Summary: The work describes the construction of a novel planar chiral [2.2]paracyclophane-based TADF-active molecule with CPL, which exhibits highly efficient luminescence performances and excellent CPL properties. The enantiomers show excellent TADF activities and the molecule has a small energy difference between singlet and triplet states. Additionally, a solution-processed yellow CP-OLEDs based on the molecule demonstrates high brightness, external quantum efficiency, and CPL signal.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Chiral Thermally Activated Delayed Fluorescence Materials Based on R/S-N2,N2′-Diphenyl-[1,1′-binaphthalene]-2,2′diamine Donor with Narrow Emission Spectra for Highly Efficient Circularly Polarized Electroluminescence

Zhi-Ping Yan et al.

Summary: Novel chiral TADF materials with high photoluminescence quantum efficiency and narrow emission spectra were prepared and showed promising performance in OLEDs, indicating potential for improving electroluminescence properties.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Semitransparent Circularly Polarized Phosphorescent Organic Light-Emitting Diodes with External Quantum Efficiency over 30% and Dissymmetry Factor Close to 10-2

Guangzhao Lu et al.

Summary: This study successfully synthesized two green chiral iridium(III) isomers using R-camphor as a chiral resource, which exhibited excellent performance in circularly polarized phosphorescent organic light-emitting diodes. By novel device engineering, the dissymmetry factor of circularly polarized electroluminescence signal was significantly boosted by one order of magnitude.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Review Chemistry, Multidisciplinary

Recent Progress of Chiral Perovskites: Materials, Synthesis, and Properties

Jiaqi Ma et al.

Summary: The combination of chiral materials and halide perovskites provides an ideal platform for designing optoelectronic and spintronic devices, with recent studies demonstrating the transfer of chirality into halide perovskites and creating chiral perovskites with various exceptional properties.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Multi-Light-Responsive Upconversion-and-Downshifting-Based Circularly Polarized Luminescent Switches in Chiral Metal-Organic Frameworks

Tonghan Zhao et al.

Summary: This study successfully constructed a dual CPL switch with light-responsive properties by loading a luminescent substance and nanoparticles into metal-organic frameworks. A reversible UC-CPL switch was realized through energy transfer, with significantly amplified asymmetry factor compared to DS-CPL. A chiroptical logic circuit with a 2D information output was designed using UV, visible, and NIR light inputs.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

3D Laser Displays Based on Circularly Polarized Lasing from Cholesteric Liquid Crystal Arrays

Xiuqin Zhan et al.

Summary: The study demonstrates full-color 3D laser displays based on circularly polarized lasers and inkjet-printed cholesteric liquid crystal arrays, showcasing vibrant colors and high fidelity in display quality.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Chiral V-shaped Pyrenes: Hexagonal Packing, Superhelix, and Amplified Chiroptical Performance

Song Hu et al.

Summary: In this study, symmetric and dissymmetric chiral V-shaped pyrenes were designed and their circular dichroism (CD) and circularly polarized excimer emission (CPEE) were investigated. Symmetric V-shaped molecules exhibited spacer-dependent CD and CPEE in molecular solution, while dissymmetric V-shaped molecules were silent in CD and CPEE. Additionally, the chiral V-shaped conformation guided a helical hexagonal packing upon self-assembly.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

High-Efficiency Circularly Polarized Electroluminescence from TADF-Sensitized Fluorescent Enantiomers

Meng Li et al.

Summary: Fluorescent enantiomers suitable for high-efficiency TADF-sensitized CP-OLEDs have been developed, exhibiting high PLQY, large kr values, and excellent performance characteristics. The resulting TADF-sensitized fluorescent devices show high EQE and low efficiency roll-off, providing a promising perspective for breaking through the EL efficiency limit of CP-FL emitters.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Polymer Science

Two Chirality Transfer Channels Assist Handedness Inversion and Amplification of Circularly Polarized Luminescence in Chiral Helical Polyacetylene Thin Films

Ming Pan et al.

Summary: This study successfully controlled the handedness and magnitude of circularly polarized luminescence (CPL) by synthesizing chiral helical polyacetylenes and observing CPL inversion and amplification in thin solid films. Changing the film-forming solvents can regulate the CPL values of the films, providing a new strategy for constructing CPL materials with tunable handedness and a large dissymmetry factor.

MACROMOLECULES (2021)

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Article Multidisciplinary Sciences

Double-helical assembly of heterodimeric nanoclusters into supercrystals

Yingwei Li et al.

Summary: DNA has long been used as a template for constructing helical assemblies of inorganic nanoparticles, but achieving helices without biological ligands is challenging. Atomically precise nanoclusters protected by ligands demonstrate hierarchical structural complexity, similar to biomolecules. The newly synthesized homodimeric and heterodimeric gold nanoclusters self-assemble into superstructures, with heterodimeric clusters forming more complex helical superstructures driven by van der Waals interactions. The surrounding ligands on the clusters contribute to the assembly through paired steric interactions.

NATURE (2021)

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Article Materials Science, Multidisciplinary

Full-Color and White Circularly Polarized Luminescence Promoted by Liquid Crystal Self-Assembly Containing Chiral Naphthalimide Dyes

Yang Li et al.

Summary: Chiral emissive nematic liquid crystals (N*-LCs) can greatly enhance circularly polarized luminescence (CPL) signals through a highly regular spiral self-assembly in the LCs system. By doping chiral NI-based dyes into nematic liquid crystals (E7, N-LCs), N*-LCs can emit standard white CPL signals by choosing the appropriate ratio of two chiral NI-based dyes.

ADVANCED OPTICAL MATERIALS (2021)

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Article Materials Science, Multidisciplinary

Blue Axially Chiral Biphenyl Based Thermally Activated Delayed Fluorescence Materials for Efficient Circularly Polarized OLEDs

Zhen-Long Tu et al.

Summary: This study introduces two axial chiral biphenyl-based blue thermally activated delayed fluorescence materials with satisfying circularly polarized luminescence properties. The strategy of axial chiral luminescence center and the close distance between chiral units may have significant effects on the properties. Circularly polarized organic light-emitting diodes doped with chiral dyes exhibit good performances.

ADVANCED OPTICAL MATERIALS (2021)

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Review Chemistry, Multidisciplinary

Recent advances in stimuli-responsive theranostic systems with aggregation-induced emission characteristics

Jing-Jing Hu et al.

Summary: The review summarizes the advancements in stimuli-responsive theranostic systems with AIE characteristics. These systems are classified based on treatment modes and stimuli types, with design strategies and application examples provided. The current state, limitations, and prospects of this technology are also discussed.

AGGREGATE (2021)

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Review Chemistry, Multidisciplinary

Pathways to increase the dissymmetry in the interaction of chiral light and chiral molecules

Jake L. Greenfield et al.

Summary: The dissymmetric interaction between circularly polarised light and chiral molecules is important across various fields, but the selectivity in absorption or emission of left-handed versus right-handed CP light is often low. Strategies to enhance this interaction include molecular design, modification of light, and creating macroscopic chiral structures, offering hope for advancements in research involving interactions of chiral molecules and light.

CHEMICAL SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Chiral polymer hosts for circularly polarized electroluminescence devices

Jayeon Hong et al.

Summary: The research has developed new polymer hosts for CP PLED applications, showing that these chiral polymer hosts play an important role in enhancing chiroptical performances and accelerating energy transfer rate.

CHEMICAL SCIENCE (2021)

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Article Materials Science, Multidisciplinary

An enantiomeric pair of alkaline-earth metal based coordination polymers showing room temperature phosphorescence and circularly polarized luminescence

Pedro Leo et al.

Summary: This work reports the synthesis and characterization of enantiomeric pair of 3D coordination polymers based on heavy alkaline-earth metal ions and cyclic aliphatic chiral linkers. These materials exhibit dense framework and intriguing photophysical properties, including intense fluorescence and long-lasting phosphorescence, as well as circularly polarized luminescence in accordance with their chiral nature.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Article Chemistry, Inorganic & Nuclear

Strong circularly polarized luminescence of mixed lanthanide coordination polymers with control of 4f electronic structures

Md Jahidul Islam et al.

Summary: This paper presents chiral mixed Eu(iii)-Ln(iii) coordination polymers (Ln = Gd and Sm) with a high dissymmetry factor of circularly polarized luminescence, achieving enhanced emission quantum yield (phi(tot) >= 50%) through control of 4f electronic structures.

DALTON TRANSACTIONS (2021)

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Article Materials Science, Multidisciplinary

Pyridinylphosphorothioate-based blue iridium(iii) complex with double chiral centers for circularly polarized electroluminescence†

Jun-Jian Lu et al.

Summary: A blue Ir(iii) complex with chiral phosphine was synthesized and showed decent circularly polarized luminescence activities. The CP-OLEDs demonstrated obvious circularly polarized electroluminescence signals, providing an efficient strategy for the design of chiral blue Ir(iii) emitters and their CP-OLEDs.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

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Review Chemistry, Multidisciplinary

Shell engineering to achieve modification and assembly of atomically-precise silver clusters

Yan Jin et al.

Summary: This review summarizes the progress in the preparation and structural determination of monolayer-protected silver clusters, focusing on the strategies and methods for precise modification and hierarchical assembly of silver clusters through shell engineering. The correlations between structure-property and structure-functionality of silver clusters are discussed, with particular emphasis on the structure-luminescence relationship and the potential of silver clusters as lighting materials. The challenges and perspectives of functional silver clusters are also highlighted, aiming to inspire the development of functionality-oriented materials based on nanosized building blocks in the fields of nanotechnology and material science.

CHEMICAL SOCIETY REVIEWS (2021)

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Article Chemistry, Multidisciplinary

Helically chiral Pd(ii) complexes containing intramolecular PdMIDLINE HORIZONTAL ELLIPSISPd metallophilicity as circularly polarized molecular phosphors

Jinqiang Lin et al.

Summary: The carbon-centered chirality is transferred to helical chirality in dinuclear and tetranuclear Pd(ii) arylacetylide complexes, resulting in phosphorescence with high quantum yields up to 50% and dissymmetry factors in the 10(-3) scale from metal-metal-to-ligand charge-transfer excited states in diluted solutions.

CHEMICAL COMMUNICATIONS (2021)

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Article Materials Science, Multidisciplinary

Thermally activated delayed fluorescence material-sensitized helicene enantiomer-based OLEDs: a new strategy for improving the efficiency of circularly polarized electroluminescence

Meng Li et al.

Summary: A new strategy of using TADF material-sensitized CPL to improve the efficiencies of CP-OLEDs is proposed. By employing helicene enantiomers with a rigid helical pi-skeleton as emitters, the study achieved enhanced efficiencies and intense CPEL.

SCIENCE CHINA-MATERIALS (2021)

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Review Chemistry, Multidisciplinary

Circularly Polarized Luminescence in Nanoassemblies: Generation, Amplification, and Application

Yutao Sang et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

AIE Triggers the Circularly Polarized Luminescence of Atomically Precise Enantiomeric Copper(I) Alkynyl Clusters

Miao-Miao Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Yellow Circularly Polarized Luminescence from C1-Symmetrical Copper(I) Complexes

Min Deng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

A C2-symmetric triple [5]helicene based on N-annulated triperylene hexaimide for chiroptical electronics

Zetong Ma et al.

SCIENCE CHINA-CHEMISTRY (2020)

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Review Chemistry, Multidisciplinary

Artificial Chiral Probes and Bioapplications

Changlong Hao et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Multifarious Chiral Nanoarchitectures Serving as Handed-Selective Fluorescence Filters for Generating Full-Color Circularly Polarized Luminescence

Biao Zhao et al.

ACS NANO (2020)

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Article Chemistry, Multidisciplinary

Chiral AuCuAu Heterogeneous Nanorods with Tailored Optical Activity

Juncai Wang et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Photoresponsive Propeller-like Chiral AIE Copper(I) Clusters

Yu-Jin Kong et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Emerging Cubic Chirality in γCD-MOF for Fabricating Circularly Polarized Luminescent Crystalline Materials and the Size Effect

Liangyu Hu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Axially Chiral TADF-Active Enantiomers Designed for Efficient Blue Circularly Polarized Electroluminescence

Meng Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

A Chiral Reduced-Dimension Perovskite for an Efficient Flexible Circularly Polarized Light Photodetector

Lin Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Physics, Applied

Helical-chiroptical nanowires generated orbital angular momentum for the detection of circularly polarized light

Zhongxuan Wang et al.

APPLIED PHYSICS LETTERS (2020)

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Article Chemistry, Multidisciplinary

Ring-Opened Hemiporphyrazines: Helical Molecules Exhibiting Circularly Polarized Luminescence

Yusuke Tanaka et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

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Review Chemistry, Inorganic & Nuclear

Self-assembly of AIEgens

Hai-Tao Feng et al.

COORDINATION CHEMISTRY REVIEWS (2020)

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Article Chemistry, Physical

Amplifying Dissymmetry Factor of Upconverted Circularly Polarized Luminescence through Chirality-Induced Spin Polarization in the Photon Upconversion Process

Tonghan Zhao et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2020)

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Article Chemistry, Physical

Circularly Polarized Luminescence from Chiral Tetranuclear Copper(I) Iodide Clusters

Li Yao et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2020)

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Article Chemistry, Physical

Bulk Chiral Halide Perovskite Single Crystals for Active Circular Dichroism and Circularly Polarized Luminescence

Yangyang Dang et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2020)

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Article Chemistry, Multidisciplinary

Solvent-Induced Sign Inversion of Circularly Polarized Luminescence: Control of Excimer Chirality by Hydrogen Bonding

Kazuto Takaishi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

Chiral 2D Organic Inorganic Hybrid Perovskite with Circular Dichroism Tunable Over Wide Wavelength Range

Jihoon Ahn et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Multidisciplinary Sciences

Ultrastable atomically precise chiral silver clusters with more than 95% quantum efficiency

Zhen Han et al.

SCIENCE ADVANCES (2020)

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Article Chemistry, Multidisciplinary

Aggregation-Induced Circularly Polarized Luminescence: Chiral Organic Materials for Emerging Optical Technologies

Andrea Nitti et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Electric-Field-Regulated Energy Transfer in Chiral Liquid Crystals for Enhancing Upconverted Circularly Polarized Luminescence through Steering the Photonic Bandgap

Xuefeng Yang et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Chiral Reticular Self-Assembly of Achiral AIEgen into Optically Pure Metal-Organic Frameworks (MOFs) with Dual Mechano-Switchable Circularly Polarized Luminescence

Weili Shang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Materials Science, Multidisciplinary

Progress in Atomically Precise Coinage Metal Clusters with Aggregation-Induced Emission and Circularly Polarized Luminescence

Miao-Miao Zhang et al.

ADVANCED OPTICAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Three-dimensional organic cage with narrowband delayed fluorescence

Hu Yingyuan et al.

SCIENCE CHINA-CHEMISTRY (2020)

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Review Chemistry, Multidisciplinary

Chiral metal phosphonates: assembly, structures and functions

Guo-Guo Weng et al.

SCIENCE CHINA-CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

DNA-Driven Two-Layer Core-Satellite Gold Nanostructures for Ultrasensitive MicroRNA Detection in Living Cells

Dan Meng et al.

SMALL (2020)

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Article Chemistry, Physical

Tailoring Circularly Polarized Luminescence of Cholesteryl Conjugated Naphthalimides via Solvent Polarity

Zhaozhen Cao et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

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Article Chemistry, Multidisciplinary

Helix-Sense-Selective Synthesis of Right- and Left-Handed Helical Luminescent Poly(diphenylacetylene)s with Memory of the Macromolecular Helicity and Their Helical Structures

Katsuhiro Maeda et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Materials Science, Multidisciplinary

Phototuning Energy Transfer in Self-Organized Luminescent Helical Superstructures for Photonic Applications

Siyang Lin et al.

ADVANCED OPTICAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Simple Perylene Diimide Cyclohexane Derivative With Combined CPL and TPA Properties

Pablo Reine et al.

FRONTIERS IN CHEMISTRY (2020)

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Article Chemistry, Multidisciplinary

Chiral Diketopyrrolopyrrole-Helicene Polymer With Efficient Red Circularly Polarized Luminescence

Kais Dhbaibi et al.

FRONTIERS IN CHEMISTRY (2020)

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Review Nanoscience & Nanotechnology

Chiral-perovskite optoelectronics

Guankui Long et al.

NATURE REVIEWS MATERIALS (2020)

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Review Chemistry, Multidisciplinary

New Perspectives to Trigger and Modulate Circularly Polarized Luminescence of Complex and Aggregated Systems: Energy Transfer, Photon Upconversion, Charge Transfer, and Organic Radical

Tonghan Zhao et al.

ACCOUNTS OF CHEMICAL RESEARCH (2020)

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Article Nanoscience & Nanotechnology

Solvent-Processed Circularly Polarized Luminescence in Light-Harvesting Coassemblies

Zhaozhen Cao et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Multidisciplinary

Chiral Functionalization of an Atomically Precise Noble Metal Cluster: Insights into the Origin of Chirality and Photoluminescence

Kumaranchira Ramankutty Krishnadas et al.

ACS NANO (2020)

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Article Chemistry, Multidisciplinary

Strategies to Achieve High Circularly Polarized Luminescence from Colloidal Organic-Inorganic Hybrid Perovskite Nanocrystals

Young-Hoon Kim et al.

ACS NANO (2020)

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Article Chemistry, Multidisciplinary

Spiranthes sinensis-Inspired Circular Polarized Luminescence in a Solid Block Copolymer Film with a Controllable Helix

Qingxiang Li et al.

ACS NANO (2020)

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Review Chemistry, Multidisciplinary

Aggregate Science: From Structures to Properties

Haoke Zhang et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Crystallization-Driven Asymmetric Helical Assembly of Conjugated Block Copolymers and the Aggregation Induced White-light Emission and Circularly Polarized Luminescence

Lei Xu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Article Chemistry, Multidisciplinary

Control of Axial Chirality by Planar Chirality Based on Optically Active [2.2]Paracyclophane

Genki Namba et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

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Review Chemistry, Inorganic & Nuclear

Chiral AIEgens - Chiral recognition, CPL materials and other chiral applications

Ming Hu et al.

COORDINATION CHEMISTRY REVIEWS (2020)

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Article Materials Science, Multidisciplinary

Color-Tunable Circularly Polarized Luminescence with Helical Polyacetylenes as Fluorescence Converters

Biao Zhao et al.

ADVANCED OPTICAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Stepwise Achievement of Circularly Polarized Luminescence on Atomically Precise Silver Clusters

Si Li et al.

ADVANCED SCIENCE (2020)

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Article Chemistry, Multidisciplinary

Axially Chiral Biphenyl Compound-Based Thermally Activated Delayed Fluorescent Materials for High-Performance Circularly Polarized Organic Light-Emitting Diodes

Zhen-Long Tu et al.

ADVANCED SCIENCE (2020)

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Article Chemistry, Multidisciplinary

Rational Design of the Platinahelicene Enantiomers for Deep-Red Circularly Polarized Organic Light-Emitting Diodes

Zhi-Ping Yan et al.

FRONTIERS IN CHEMISTRY (2020)

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Review Chemistry, Multidisciplinary

Beyond Chiral Organic (p-Block) Chromophores for Circularly Polarized Luminescence: The Success of d-Block and f-Block Chiral Complexes

Benjamin Doistau et al.

FRONTIERS IN CHEMISTRY (2020)

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Article Nanoscience & Nanotechnology

Noncovalently Modulated Chiral Nanoclays for Circularly Polarized Luminescence Color Conversion

Juncong Liang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Multidisciplinary

Designing Hybrid Chiral Photonic Films with Circularly Polarized Room-Temperature Phosphorescence

Mingcong Xu et al.

ACS NANO (2020)

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Article Chemistry, Multidisciplinary

Maximizing Chiral Perturbation on Thermally Activated Delayed Fluorescence Emitters and Elaboration of the First Top-Emission Circularly Polarized OLED

Lucas Frederic et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Enantiomeric MOF Crystals Using Helical Channels as Palettes with Bright White Circularly Polarized Luminescence

Chong Zhang et al.

ADVANCED MATERIALS (2020)

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Article Chemistry, Physical

Mechanically Controlled and Consecutively Boosted Circularly Polarized Luminescence of Nanoassemblies from Achiral Molecules

Yutao Sang et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

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Article Chemistry, Multidisciplinary

Highly Distorted Chiral Two-Dimensional Tin Iodide Perovskites for Spin Polarized Charge Transport

Haipeng Lu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Polymer Science

Circularly Polarized Luminescence and Tunable Helical Assemblies of Aggregation-Induced Emission Amphiphilic Polytriazole Carrying Chiral L-Phenylalanine Pendants

Qiuming Liu et al.

MACROMOLECULES (2020)

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Review Chemistry, Multidisciplinary

Chiroptical Properties in Thin Films of π-Conjugated Systems

Gianluigi Albano et al.

CHEMICAL REVIEWS (2020)

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Article Multidisciplinary Sciences

Ligand engineering to achieve enhanced ratiometric oxygen sensing in a silver cluster-based metal-organic framework

Xi-Yan Dong et al.

NATURE COMMUNICATIONS (2020)

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Article Chemistry, Physical

Enhanced Synchronously Emission Dissymmetry Factor and Quantum Efficiency of Circularly Polarized Phosphorescence from Point-Chiral Cyclometalated Platinum(II) Liquid Crystal

Bo Yang et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

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Article Chemistry, Multidisciplinary

Amplifiable Symmetry Breaking in Aggregates of Vibrating Helical Molecules

Fang Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Chemistry, Multidisciplinary

Circularly Polarized Thermally Activated Delayed Fluorescence Emitters in Through-Space Charge Transfer on Asymmetric Spiro Skeletons

Sheng-Yi Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

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Article Polymer Science

Aggregation-Induced Emission-Active Chiral Helical Polymers Show Strong Circularly Polarized Luminescence in Thin Films

Na Lu et al.

MACROMOLECULES (2020)

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Article Chemistry, Multidisciplinary

Optically Active Perovskite CsPbBr3 Nanocrystals Helically Arranged on Inorganic Silica Nanohelices

Peizhao Liu et al.

NANO LETTERS (2020)

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Article Chemistry, Physical

Intercluster aurophilicity-driven aggregation lighting circularly polarized luminescence of chiral gold clusters

Zhen Han et al.

NANO RESEARCH (2020)

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Article Materials Science, Multidisciplinary

Photoinvertible Chiral Liquid Crystal that Affords Helicity-Controlled Aromatic Conjugated Polymers

Satoru Yoshida et al.

ADVANCED OPTICAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Spontaneous Resolution of Chiral Multi-Thiolate-Protected Ag30 Nanoclusters

Jia-Hong Huang et al.

ACS CENTRAL SCIENCE (2020)

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Article Nanoscience & Nanotechnology

Dual Stimuli-Responsive High-Efficiency Circularly Polarized Luminescence from Light-Emitting Chiral Nematic Liquid Crystals

Youde Chen et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Polymer Science

High-Efficiency Circularly Polarized Luminescence from Chiral Luminescent Liquid Crystalline Polymers with Aggregation-Induced Emission Properties

Zhi-Wang Luo et al.

MACROMOLECULES (2020)

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Article Multidisciplinary Sciences

Sequentially amplified circularly polarized ultraviolet luminescence for enantioselective photopolymerization

Dongxue Han et al.

NATURE COMMUNICATIONS (2020)

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Review Chemistry, Multidisciplinary

Organic luminescent materials: The concentration on aggregates from aggregation-induced emission

Jie Yang et al.

AGGREGATE (2020)

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Article Multidisciplinary Sciences

Direct detection of circular polarized light in helical 1D perovskite-based photodiode

A. Ishii et al.

SCIENCE ADVANCES (2020)

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Review Chemistry, Multidisciplinary

Circularly polarized luminescence of nanoassembliesviamulti-dimensional chiral architecture control

Wenjie Chen et al.

NANOSCALE (2020)

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Article Chemistry, Multidisciplinary

Recyclable CPL switch regulated by using an applied DC electric field from chiral nematic liquid crystals (N*-LCs)

Xiaojing Li et al.

MATERIALS CHEMISTRY FRONTIERS (2020)

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Article Chemistry, Multidisciplinary

Lanthanide MOFs for inducing molecular chirality of achiral stilbazolium with strong circularly polarized luminescence and efficient energy transfer for color tuning

Min Zeng et al.

CHEMICAL SCIENCE (2020)

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Article Chemistry, Multidisciplinary

An axially chiral thermally activated delayed fluorescent emitter with a dual emitting core for a highly efficient organic light-emitting diode

Yin-Feng Wang et al.

CHEMICAL COMMUNICATIONS (2020)

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Article Materials Science, Multidisciplinary

Enabling discrimination capability in an achiral F6BT-based organic semiconductor transistor via circularly polarized light induction

Junjie Cheng et al.

JOURNAL OF MATERIALS CHEMISTRY C (2020)

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Article Chemistry, Multidisciplinary

A self-assembled nanohelix for white circularly polarized luminescence via chirality and energy transfer

Sijia Ma et al.

NANOSCALE (2020)

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Article Materials Science, Multidisciplinary

Circularly polarized luminescence from AIEgens

Fengyan Song et al.

JOURNAL OF MATERIALS CHEMISTRY C (2020)

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Review Chemistry, Multidisciplinary

Recent advances in circularly polarized electroluminescence based on organic light-emitting diodes

Da-Wei Zhang et al.

CHEMICAL SOCIETY REVIEWS (2020)

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Article Chemistry, Multidisciplinary

Time-controllable roll-up onset of polythiophene sheets into nanotubes that exhibit circularly polarized luminescence

N. Kameta et al.

NANOSCALE (2020)

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Article Chemistry, Multidisciplinary

Multi-color tunable circularly polarized luminescence in one single AIE system

Hongxing Shang et al.

CHEMICAL SCIENCE (2020)

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Article Chemistry, Multidisciplinary

Sign inversions of circularly polarized luminescence for helical compounds by chemically fine-tuning operations

Wei-Bin Lin et al.

CHEMICAL COMMUNICATIONS (2020)

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Article Materials Science, Multidisciplinary

Circularly polarized luminescence from semiconductor quantum rods templated by self-assembled cellulose nanocrystals

Yue Shi et al.

JOURNAL OF MATERIALS CHEMISTRY C (2020)

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Review Nanoscience & Nanotechnology

Recent advances in optical metasurfaces for polarization detection and engineered polarization profiles

Yuttana Intaravanne et al.

NANOPHOTONICS (2020)

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Article Chemistry, Multidisciplinary

Experimental and theoretical studies on circularly polarized phosphorescence of a [2.2]paracyclophane-based platinum(ii) complex

Ryo Inoue et al.

CHEMICAL COMMUNICATIONS (2020)

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Article Chemistry, Multidisciplinary

2,2-Diamino-6,6′-diboryl-1,1′-binaphthyl: A Versatile Building Block for Temperature-Dependent Dual Fluorescence and Switchable Circularly Polarized Luminescence

Zuo-Bang Sun et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Materials Science, Multidisciplinary

1,8-Naphthalimide-based circularly polarized TADF enantiomers as the emitters for efficient orange-red OLEDs

Yin-Feng Wang et al.

ORGANIC ELECTRONICS (2019)

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Article Physics, Multidisciplinary

Circularly polarized light detector based on 2D embedded chiral nanostructures

Wang Xiao et al.

PHYSICA SCRIPTA (2019)

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Article Chemistry, Multidisciplinary

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Noticeable Chiral Center Dependence of Signs and Magnitudes in Circular Dichroism (CD) and Circularly Polarized Luminescence (CPL) Spectra of alt-trans-Poly(9,9-dialkylfluorene-2,7-vinylene)s Bearing Chiral Alkyl Side Chains in Solution, Aggregates, and Thin Films

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Site-selective photoinduced cleavage and profiling of DNA by chiral semiconductor nanoparticles

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Aggregation-induced CPL response from chiral binaphthyl-based AIE-active polymers via supramolecular self-assembled helical nanowires

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Significant Enhancement of Absorption and Luminescence Dissymmetry Factors in the Far-Red Region: A Zinc(II) Homoleptic Helicate Formed by a Pair of Achiral Dipyrromethene Ligands

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Amino-acid- and peptide-directed synthesis of chiral plasmonic gold nanoparticles

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Enantiopure (P)- and (M)-3,14-bis(o-hydroxyaryl)tetrahydrobenzo[5] helicenediols and their helicene analogues: Synthesis, amplified circularly polarized luminescence and catalytic activity in asymmetric hetero-Diels-Alder reactions

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Synthesis, Structures, Resolution, and Chiroptical Properties of 1,16-Diaryl-Substituted Benzo[5] helicene Derivatives

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Synthesis, Structures, and Photophysical Properties of Optically Stable 1,16-Dipheny1-3,14-diaryl-Substituted Tetrahydrobenzo[5]helicenediol Derivatives: Enantioselective Recognition toward Tryptophan Methyl Esters

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Amplification of Circularly Polarized Luminescence through Triplet Triplet Annihilation-Based Photon Upconversion

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Oligo- and Polyfluorenes Meet Cellulose Alkyl Esters: Retention, Inversion, and Racemization of Circularly Polarized Luminescence (CPL) and Circular Dichroism (CD) via Intermolecular C-H/O=C Interactions

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Limonene induced chiroptical generation and inversion during aggregation of achiral polyfluorene analogs: structure-dependence and mechanism

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Tuning the Photoresponse in Organic Field-Effect Transistors

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Structural Origin of Circularly Polarized Iridescence in Jeweled Beetles

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Gold Helix Photonic Metamaterial as Broadband Circular Polarizer

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Extraordinary circularly polarized luminescence activity exhibited by cesium tetrakis(3-heptafluoro-butylryl-(+)-camphorato) Eu(III) complexes in EtOH and CHCl3 solutions

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Tunable circularly polarized lasing emission in reflection distributed feedback dye lasers

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Quantum teleportation between light and matter

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Chiroptical properties induced in chiral photonic-bandgap liquid crystals leading to a highly efficient laser-feedback effect

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Origin of strong chiroptical activities in films of nonafluorenes with a varying extent of pendant chirality

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Modified BINOL ligands in asymmetric catalysis

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