4.8 Article

Enhancement of lithium-mediated ammonia synthesis by addition of oxygen

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Multidisciplinary

Domino Effect: Gold Electrocatalyzing Lithium Reduction to Accelerate Nitrogen Fixation

Lin-Feng Gao et al.

Summary: The research demonstrates that Au/CP can effectively catalyze the production of NH3 in Li-mediated NRR in non-aqueous solutions. Au improves electron transfer kinetics, promotes the formation of Li, and accelerates NRR. The NH3 yield from NRR reaches up to 50 μg h(-1) cm(-2).

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Physical

In-Depth Characterization of Lithium-Metal Surfaces with XPS and ToF-SIMS: Toward Better Understanding of the Passivation Layer

Svenja-K Otto et al.

Summary: Research indicates that a nanometer-thick passivation layer on the surface of lithium metal consists of an outer lithium hydroxide and carbonate layer, and an inner region rich in lithium oxide. The thickness and composition of the passivation layer depend on treatment and storage conditions. Guidelines for experimental design and data interpretation are provided to ensure reliable and comparable experimental results.

CHEMISTRY OF MATERIALS (2021)

Review Chemistry, Multidisciplinary

Electrochemical ammonia synthesis: Mechanistic understanding and catalyst design

Huidong Shen et al.

Summary: NH3 production currently relies on the energy-intensive Haber-Bosch process, but electrochemical NH3 synthesis powered by renewable electricity offers a promising carbon-neutral and sustainable strategy. However, significant enhancements in energy efficiency, conversion rate, and durability are still needed, achievable only through the design of efficient electrocatalysts.
Article Multidisciplinary Sciences

Nitrogen reduction to ammonia at high efficiency and rates based on a phosphonium proton shuttle

Bryan H. R. Suryanto et al.

Summary: Ammonia (NH3) is a globally important commodity for fertilizer production, but its synthesis by the Haber-Bosch process causes substantial emissions of carbon dioxide. Alternative methods being explored include the promising electrochemical lithium-mediated nitrogen reduction reaction, which has required sacrificial sources of protons. In this study, a phosphonium salt is introduced as a proton shuttle to help resolve this limitation, resulting in high NH3 production rates and demonstrated continuous operation for more than 3 days.

SCIENCE (2021)

Article Chemistry, Multidisciplinary

Towards understanding of electrolyte degradation in lithium-mediated non-aqueous electrochemical ammonia synthesis with gas chromatography-mass spectrometry

Rokas Sazinas et al.

Summary: The liquid electrolytes after electrochemical ammonia synthesis can be analyzed using GCMS and EI-MS techniques to determine molecular composition and byproduct formation mechanisms.

RSC ADVANCES (2021)

Article Multidisciplinary Sciences

Methods for nitrogen activation by reduction and oxidation

Haldrian Iriawan et al.

Summary: The article introduces the importance of the industrial Haber-Bosch process for producing ammonia in modern society, discusses the challenges of N-2 activation and the drawbacks of the Haber-Bosch process, proposes new strategies for sustainable N-2 activation, compares the latest research results from different catalytic reactions, and discusses best practices for improving reproducibility and cost-effective methods for rigorous experimentation.

NATURE REVIEWS METHODS PRIMERS (2021)

Review Chemistry, Multidisciplinary

Recent progress in electrochemical synthesis of ammonia from nitrogen: strategies to improve the catalytic activity and selectivity

Bing Yang et al.

Summary: The modern ammonia synthesis industry established by Haber-Bosch in 1913 has changed the history of food production but its reliance on fossil fuels brings significant energy consumption and CO2 emissions. Electrochemical ammonia synthesis, as a green and sustainable alternative, has the potential to reduce fossil fuel consumption and CO2 emissions.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

Review Chemistry, Multidisciplinary

Liquefied Sunshine: Transforming Renewables into Fertilizers and Energy Carriers with Electromaterials

Douglas R. MacFarlane et al.

ADVANCED MATERIALS (2020)

Article Multidisciplinary Sciences

DMF stabilized Li3N slurry for manufacturing self-prelithiatable lithium-ion capacitors

Cuilian Liu et al.

SCIENCE BULLETIN (2020)

Review Chemistry, Physical

A Roadmap to the Ammonia Economy

Douglas R. MacFarlane et al.

Article Chemistry, Physical

Subsurface Nitrogen Dissociation Kinetics in Lithium Metal from Metadynamics

Thomas Ludwig et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2020)

Article Multidisciplinary Sciences

Identification and elimination of false positives in electrochemical nitrogen reduction studies

Jaecheol Choi et al.

NATURE COMMUNICATIONS (2020)

Article Chemistry, Multidisciplinary

Increasing stability, efficiency, and fundamental understanding of lithium-mediated electrochemical nitrogen reduction

Suzanne Z. Andersen et al.

ENERGY & ENVIRONMENTAL SCIENCE (2020)

Article Chemistry, Physical

A theoretical explanation of the effect of oxygen poisoning on industrial Haber-Bosch catalysts

Brian A. Rohr et al.

JOURNAL OF CATALYSIS (2019)

Article Multidisciplinary Sciences

A rigorous electrochemical ammonia synthesis protocol with quantitative isotope measurements

Suzanne Z. Andersen et al.

NATURE (2019)

Article Multidisciplinary Sciences

Electrified methane reforming: A compact approach to greener industrial hydrogen production

Sebastian T. Wismann et al.

SCIENCE (2019)

Article Chemistry, Physical

Strategies toward Selective Electrochemical Ammonia Synthesis

Aayush R. Singh et al.

ACS CATALYSIS (2019)

Article Multidisciplinary Sciences

Quantifying inactive lithium in lithium metal batteries

Chengcheng Fang et al.

NATURE (2019)

Editorial Material Chemistry, Physical

The Difficulty of Proving Electrochemical Ammonia Synthesis

Jakob Kibsgaard et al.

ACS ENERGY LETTERS (2019)

Article Chemistry, Physical

Electrifying the Haber–Bosch

Marcal Capdevila-Cortada

Nature Catalysis (2019)

Article Chemistry, Physical

Understanding Continuous Lithium-Mediated Electrochemical Nitrogen Reduction

Nikifar Lazouski et al.

Article Chemistry, Physical

XPS on Li-Battery-Related Compounds: Analysis of Inorganic SEI Phases and a Methodology for Charge Correction

Kevin N. Wood et al.

ACS APPLIED ENERGY MATERIALS (2018)

Article Chemistry, Multidisciplinary

Ammonia synthesis from N2 and H2O using a lithium cycling electrification strategy at atmospheric pressure

Joshua M. McEnaney et al.

ENERGY & ENVIRONMENTAL SCIENCE (2017)

Review Chemistry, Multidisciplinary

Electrolytes and Interphases in Li-Ion Batteries and Beyond

Kang Xu

CHEMICAL REVIEWS (2014)

Review Chemistry, Multidisciplinary

Challenges in reduction of dinitrogen by proton and electron transfer

Cornelis J. M. van der Ham et al.

CHEMICAL SOCIETY REVIEWS (2014)

Article Instruments & Instrumentation

Design and test of a flexible electrochemical setup for measurements in aqueous electrolyte solutions at elevated temperature and pressure

Gustav K. H. Wiberg et al.

REVIEW OF SCIENTIFIC INSTRUMENTS (2014)

Article Geosciences, Multidisciplinary

How a century of ammonia synthesis changed the world

Jan Willem Erisman et al.

NATURE GEOSCIENCE (2008)

Article Chemistry, Applied

Towards an ammonia-mediated hydrogen economy?

CH Christensen et al.

CATALYSIS TODAY (2006)

Review Thermodynamics

Air separation and liquefaction: recent developments and prospects for the beginning of the new millennium

WF Castle

INTERNATIONAL JOURNAL OF REFRIGERATION-REVUE INTERNATIONALE DU FROID (2002)