4.8 Article

Cellulose tailored semiconductors for advanced photocatalysis

期刊

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.rser.2021.111820

关键词

Cellulose; Semiconductor; Bio-template; Monolith; Photocatalysis

资金

  1. Natural Science Foundation of Jiangsu Province Youth Fund [BK20210628]
  2. Forestry Science and Technology Innovation and Extension Project of Jiangsu Province [LYKJ[2021]04]

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Organic-inorganic composites featuring cellulose tailored semiconductors exhibit tunable properties and diverse applications, with unique fibrous structure and abundant surface functional groups. Challenges and future directions for the modification of cellulose into semiconductors are also addressed in this review.
In recent years, organic-inorganic composites have aroused considerable attention due to their tunable properties, where cellulose tailored semiconductors for artificial photocatalysis are typical examples. In virtue of the unique fibrous structure and abundant surface functional groups, cellulose employed in the design of photocatalysts could endow good hydrophilicity, dispersity, stability, high porosity, conductivity, large surface area and even unexpected morphologies. In this review, the modification strategies of cellulose to semiconductors (function as assistants and sacrifice as bio-templates), diverse monoliths (films, gels and textiles) and their photocatalytic applications (contaminants treatment and H-2 production) are summarized in detail. In addition, the challenges and outlook of semiconductor/cellulose photocatalysts are also discussed.

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