期刊
INORGANIC CHEMISTRY COMMUNICATIONS
卷 71, 期 -, 页码 50-53出版社
ELSEVIER
DOI: 10.1016/j.inoche.2016.07.004
关键词
Metal tungstates; Nanowires; f-f transitions; Luminescent thermometer
资金
- National Science Foundation of China [21501006, 21405005, 21301009]
- Foundation of Henan Educational Committee [15A150002, 15A150031]
SrWO4:Eu3+ nanowires with high aspect ratio were prepared by a solvothermal method via a poor solvent induced self-assembly process. The luminescence properties of SrWO4:Eu3+ nanowires were investigated in detail. In the emission spectrum excited at 277 nm, the D-5(0) -> F-7(2) is much stronger than the D-5(0) -> F-7(1), indicating that Eu3+ ions occupy low symmetry sites in SrWO4 lattices. The broad excitation band centered at 277 nm is assigned to the overlap of WO42- absorption and charge transfer transition between Eu3+ and O2-. The temperature-dependent luminescent properties are also investigated in a wide temperature range from 100 to 450 K, it reveals that SrWO4:Eu3+ is a potential luminescent thermometer in the temperature range from 310 K to 450 K. (C) 2016 Elsevier B.V. All rights reserved.
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