期刊
INORGANIC CHEMISTRY
卷 55, 期 19, 页码 9696-9706出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b01473
关键词
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资金
- Russian Foundation for Basic Research [16-33-00464 mol_a]
- Presidium of the Russian Academy of Sciences [35]
In this article we report the synthesis and structure of the new Co(II) complex Et4N[Co-II(hfac)(3)] (I) (hfac = hexafluoroacetylacetonate) exhibiting single-ion magnet (SIM) behavior. The performed analysis Of the magnetic characteristics based on the complementary experimental techniques such as static and dynamic magnetic measurements, electron paramagnetic resonance spectroscopy in conjunction with the theoretical modeling (parametric Hamiltonian and ab initio calculations) demonstrates that the SIM properties of I arise from the nonuniaxial magnetic anisotropy with strong positive axial and significant rhombic contributions.
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