4.7 Article

Polymer-corrosion inhibitor conjugates as additives for anticorrosion application

期刊

PROGRESS IN ORGANIC COATINGS
卷 163, 期 -, 页码 -

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.porgcoat.2021.106639

关键词

Controlled release; Corrosion inhibitor; Leaching; Responsive polymer; Smart coating

资金

  1. Thailand Science Research and Innovation (TSRI) [FRB650023/0457]
  2. Vidyasirimedhi Institute of Science and Technology
  3. Frontier Research Center (FRC) at VISTEC

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A new anticorrosive additive based on polymer-corrosion inhibitor conjugate has been developed to control the release of corrosion inhibitors in commercial epoxy coatings, showing superior performance in slowing the leaching of corrosion inhibitors and enhancing anticorrosion properties. The use of polymer-corrosion inhibitor conjugates as efficient additives in coatings offers a promising strategy for the development and commercialization of materials with high corrosion protection and environmental responsibility.
Uncontrolled leaching of inhibitors from coatings containing corrosion inhibitors into the environment, even when corrosion does not occur, causes environmental pollution and reduces the anticorrosion performance. To overcome these issues, we developed a new anticorrosive additive for commercial epoxy coatings based on a polymer-corrosion inhibitor conjugate which can control the release of corrosion inhibitors when corrosion occurs. Coatings containing the responsive additives induce a slower leaching of corrosion inhibitor and a better anticorrosion performance compared to coatings containing entrapped corrosion inhibitor at the same concentration. Indeed, the corrosion rate of steel coated with an epoxy coating containing the polymer-inhibitor conjugate is similar to 3 times lower than for the coating containing the non-conjugated inhibitor. We show hence that polymer-corrosion inhibitor conjugates can be employed as efficient additives in commercial coatings. This strategy opens new avenues for the development and commercialization of materials with high corrosion protection which are environmentally responsible.

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