期刊
PROGRESS IN ORGANIC COATINGS
卷 159, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.porgcoat.2021.106441
关键词
Graphene oxide; 5-Amino-1; 3; 4-thiadiazole-2-thiol; Low temperature; Anti-corrosion; Freezing
资金
- National Natural Science Foundation of China [51901216]
- China Postdoctoral Science Foundation [2019M652471, 2020T130620]
The study showed that the modified AMT-GO/EP coating exhibited better dispersity and more significant corrosion protection. Additionally, coatings performed worse at low temperatures due to accelerated diffusion of corrosive media caused by freezing.
In this study, the 5-Amino-1,3,4-thiadiazole-2-thiol grafted graphene oxide (AMT-GO) composite was synthesized and the corrosion protection properties of the neat EP, GO/EP and AMT-GO/EP coatings at the ambient and low temperatures were comparatively studied. Based on the experimental results, AMT is anchored on GO mainly via the reactions between -NH2 and -SH of AMT and -COOH and -CH(O)CH- of GO. After modification, the dispersity of the GO nanosheets is significantly improved. As the filler, both of the GO and AMT-GO nanoplatforms could enhance the protective ability of the polymer coating, the latter possessing the more remarkable effect because of its better dispersity and the beneficial impact provided by exposed -NH2 and -SH. All of the three coatings exhibit worse anti-corrosion performance at the low temperature than the ambient temperature, because the diffusion of corrosive media across the polymer matrix and along the substrate/coating interface could be accelerated by freezing.
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