期刊
INORGANIC CHEMISTRY
卷 55, 期 13, 页码 6685-6691出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b00925
关键词
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资金
- NSFC [21475078, 21271120, 21301109, 21501111]
- 973 Program [2012CB821705, 2013CB933800]
- Taishan Scholar's Construction Project
- Reward Fund for Outstanding Young and Middle Aged Scientists of Shandong Province [BS2012CL032]
- Jinan Science and Technology Bureau [OUT_06623]
A new composite Au@Cu(II)-MOF catalyst has been synthesized via solution impregnation and full characterized by HRTEM, SEM-EDS, XRD, gas adsorption-desorption, XPS, and ICP analysis. It has been shown here that the Cu(II)-framework can be a useful platform to stabilize and support gold nanoparticles (Au NPs). The obtained Au@Cu(II)-MOF exhibits a bifunctional catalytic behavior and is able to promote selective aerobic benzyl alcohol oxidation-Knoevenagel condensation in a stepwise way.
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