期刊
INORGANIC CHEMISTRY
卷 55, 期 20, 页码 10118-10121出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b01921
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资金
- German Science Foundation [DEG-K0 2288/20-1]
- Jacobs University
- CMST COST Action (PoCheMoN) [CM1203]
- Hungarian Scientific Research Fund [K-109029]
- MINECO [CTQ2014-52774-P]
- Generalitat de Catalunya [2014SGR199, XRQTC]
- ICREA foundation for an ICREA ACADEMIA award
We have synthesized and structurally characterized the first discrete thallium-containing polyoxometalate, [Tl-2{B-beta-SiW8O30 (OH)}(2)](12-) (1). Polyanion 1 was characterized in the solid-state and shown to be solution-stable by Tl-203/205 NMR, electrospray ionization mass spectrometry, and electrochemical studies. The antibacterial activity of 1 was also investigated.
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