期刊
INORGANIC CHEMISTRY
卷 55, 期 20, 页码 10793-10799出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b01858
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资金
- Marie Curie Action [PIOF-GA-2013-622439]
- Spanish Consolider Ingenio Program [CSD2007-00045]
- Spanish government MEC [MAT2013-46649-C4-1/3-P]
- Deep Carbon Observatory
- National Science Foundation - Earth Sciences [EAR-1128799]
- Department of - Energy - GeoSciences [DE-FG02-94ER14466]
- DOE Office of Science [DE-AC02-06CH11357]
- COMPRES under NSF [EAR 11-57758]
- Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
- COMPRES, the Consortium for Materials Properties Research in Earth Sciences under NSF [EAR 10-43050]
- Directorate For Geosciences [1522560] Funding Source: National Science Foundation
- Division Of Earth Sciences [1522560] Funding Source: National Science Foundation
The role of carbon dioxide, CO2, as oxidizing agent at high pressures and temperatures is evaluated by studying its chemical reactivity with three transition metals: Au, Pt, and Re. We report systematic X-ray diffraction measurements up to 48 GPa and 2400 K using synchrotron radiation and laser-heating diamond-anvil cells. No evidence of reaction was found in Au and Pt samples in this pressure temperature range. In the Re + CO2 system, however, a strongly driven redox reaction occurs at P > 8 GPa and T > 1500 K, and orthorhombic beta-ReO2 is formed. This rhenium oxide phase is stable at least up to 48 GPa and 2400 K and was recovered at ambient conditions. Raman spectroscopy data confirm graphite as a reaction product. Ab-initio total-energy structural and compressibility data of the beta-ReO2 phase shows an excellent agreement with experiments, altogether accurately confirming CO, reduction P T conditions in the presence of rhenium metal' and the beta-ReO2 equation of state.
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