期刊
POLYMER COMPOSITES
卷 42, 期 12, 页码 6816-6826出版社
WILEY
DOI: 10.1002/pc.26342
关键词
Diels-Alder reaction; phase change materials; polyethylene glycol; recyclable; thermal conductivity
资金
- National Key Research and Development Plan of China [2018YFB1107305]
- Zhejiang Provincial Natural Science Foundation, China [LTZ20E020001]
A SSPCMs was developed using dynamic thermal reversible Diels-Alder bonds to address the leakage and poor shape stability issues during phase transformation. The addition of Halloysite nanotubes decorated with Fe3O4 nanoparticles improved the thermal conductivity of SSPCMs significantly. The best overall properties of SSPCMs were achieved with a filler content of 0.5 wt%, showing promising energy-saving and environmentally friendly thermal management capabilities.
The permanently chemically cross-linking solid-solid phase change materials (SSPCMs) were designed to solve the problem of leakage and poor shape stability during the whole process of phase transformation. However, these materials lead to environment pollution and resources waste because of the non-recyclability. Therefore, a SSPCMs was fabricated using dynamic thermal reversible Diels-Alder bonds. The prepared SSPCMs exhibited excellent shape, heat storage stability, and reliability and reprocessed ability, resulting from dynamic Diels-Alder bonds. Moreover, the Halloysite nanotubes decorated with Fe3O4 nanoparticles (HNTs@Fe3O4) were used to enhance the thermal conductivity of SSPCMs. When the filler content was 0.5 wt%, the best integrated properties (phase change properties and thermal conductivity) of the SSPCMs were obtained, it had the highest melting and freezing phase change enthalpies about 116.8 and 127.2 J/g, and thermal conductivity value, 0.223 W/m K, which was 101% higher than pure SSPCMs. Hence, the prepared SSPCMs can be considered as promising save-energy, friendly-environment thermal management materials.
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