期刊
POLYMER COMPOSITES
卷 43, 期 4, 页码 2022-2033出版社
WILEY
DOI: 10.1002/pc.26516
关键词
crystal; molecular structure; sisal fiber; surface properties; thermal degradation; thermoplastic cassava starch
资金
- Guangxi Natural Science Foundation of China [2020GXNSFAA159113]
- National Natural Science Foundation of China [51663002]
The effects of sisal fiber content and its surface treatment on the thermal degradation behavior and structures of thermoplastic cassava starch composites were investigated. It was found that increasing fiber content can enhance the thermal decomposition temperature, and sisal fiber treated with sodium hydroxide showed better thermal stability.
The thermoplastic cassava starch (TPS)/sisal fiber (SF) composites were prepared by melt blending. The effects of SF content and its surface treated by sodium hydroxide (NaOH) and silane coupling agent (KH550) on the thermal degradation behavior and structures of TPS were investigated by thermogravimetric-mass spectrometry (TG-MS), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and nuclear magnetic resonance (NMR). The thermal decomposition temperatures of TPS/SF composites increase with the SF content. The thermal decomposition products of TPS/SF composites are mainly methane, H2O, acetylene, formaldehyde, methanol and CO2. The thermal stability of composites containing SF treated by NaOH is better than that of KH550. TPS/SF composites show A + V types crystal, and the sample containing SF treated by NaOH has the highest V type crystal. The experimental results reveal that the content and the surface of SF play an important role in the thermal stability and structures changes of TPS/SF composites.
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