期刊
INORGANIC CHEMISTRY
卷 55, 期 17, 页码 8257-8259出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b01453
关键词
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资金
- National Natural Science Foundations of China [21303018, 21371033, 21401195]
- Natural Science Foundation for Young Scholars of Fujian Province [2015J05041]
- State Key Laboratory of Structural Chemistry of China [20150001, 20160020]
A step-by-step synthetic strategy, setting up a bridge between the polyoxometalate (POM) and metal halide cluster (MHC) systems, is demonstrated to construct an unprecedented composite hybrid cluster built up from one high-nuclearity cationic MHC [Cu8I6](2+) and eight Anderson-type anionic POMs [HCrMo6O18(OH)(6)](2-) cross-linked by a tripodal alcohol derivative.
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