4.7 Article

Organocatalytic PET-RAFT polymerization with a low ppm of organic photocatalyst under visible light

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Summary: Organocatalytic atom transfer radical polymerization (O-ATRP) is a promising method for metal-free polymer synthesis, but using catalysts at low loading levels remains a challenge. By designing catalysts based on heteroatom-doped polycyclic arenes, oxygen-doped anthanthrene was discovered as an efficient organic photoredox catalyst for O-ATRP, allowing controlled polymerization at low catalyst loading levels.

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