期刊
POLYMER
卷 240, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2021.124488
关键词
Encapsulation; Miniemulsion polymerization; Cellulose nanocrystal; Acrylic monomers; Surface modification; Functionalization
资金
- P3Nano program in the US Endowment for Forestry and Communities
- National Science Foundation [ECCS-2025462]
This study demonstrates the encapsulation of cellulose nanocrystals (CNCs) in acrylic particles through miniemulsion polymerization, utilizing costabilizer, water soluble initiator, and comonomer mixtures. Functionalized CNCs were successfully incorporated while unmodified CNCs were located outside the formed latex particles. It highlights the challenge of using polar and reactive surface modifiers for CNCs in polymerization.
Cellulose nanocrystals (CNCs) show promise for enhancing properties of waterborne latexes and coatings. Miniemulsion polymerization is a promising route to obtaining well-controlled latex distributions sufficient to encapsulate CNCs in the monomer phase. Here, we demonstrate the first miniemulsion polymerization resulting in encapsulation of CNCs that incorporates costabilizer, water soluble initiator, and comonomer mixtures, aspects that are important for practical implementation. CNCs were added to the monomer phase as either unmodified (umCNC) or one of two functionalized forms: modified with isocyanatoethyl methacrylate (mCNC, containing a polymerizable vinyl group) or grafted with butyl acrylate/methyl methacrylate copolymer (gmCNC). The gmCNCs were incorporated successfully into acrylic particles. In contrast, the umCNCs were located outside the formed latex particles. Interestingly, the mCNCs coagulated during the polymerization, highlighting the challenge of utilizing polar and reactive acryloyl CNC surface modifiers that lead to migration from the droplet phase.
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