4.7 Article

Experimental investigation on the thermo-mechanical deformation of thermo-induced shape memory polyurethane

期刊

POLYMER
卷 237, 期 -, 页码 -

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.polymer.2021.124337

关键词

Shape memory polyurethane; Thermo-mechanical deformation history; Cyclic shape memory effect; Internal stress; Rate dependence

资金

  1. National Natural Science Foundation of China [12072295, 11572265]
  2. Foundation of Key Laboratory of National Defense Science and Technology [6142202190203]
  3. Applied Basic Research Project of Sichuan Province [2021YJ0050]

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The study investigates the influences of loading conditions on the shape memory effect of thermo-induced shape memory polyurethane through thermo-mechanical deformation experiments. The results show that there is a linear relationship between internal stress and recovery ratio under different strain rates and number of cycles, which can reflect the influence of deformation history on the shape memory effect. These findings contribute to a deeper understanding of shape memory effect and the establishment of a constitutive model considering the thermo-mechanical deformation history of TSMPU.
The influences of loading conditions on the shape memory effect (SME) of thermo-induced shape memory polyurethane (TSMPU) are investigated by series of thermo-mechanical deformation experiments. The variables related to mechanical responses and the strain contours are extracted to analyze the SME. It is shown that the recovery ratio gradually decreases and the residual strain gradually accumulates with the increase of number of cycles. Then, the internal stress is obtained from the experimental results under different deformation histories. It is unexpectedly found that there is a linear relationship between the internal stress and recovery ratio under the same peak strain with different strain rates and number of cycles. Meanwhile, the formation and release of internal stress as the deformation mechanism can reasonably reflect the influence of deformation history on the SME. The experimental results are useful to deepen the understanding of SME and establish a constitutive model considering the thermo-mechanical deformation history of TSMPU.

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