期刊
INORGANIC CHEMISTRY
卷 56, 期 1, 页码 269-276出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b02126
关键词
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资金
- Czech Science Foundation [P206/11/0727]
- Institute of Organic Chemistry and Biochemistry AS CR, v.v.i. [RVO 61388963]
- U.S. National Science Foundation [CHE-1566435]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1566435] Funding Source: National Science Foundation
Anodic oxidation of [CB11H12](-) and 18 of its halogenated and/or methylated derivatives was examined. Reversible oxidation was found for four of the anions in liquid SO2 and for four more in 1,1,1,3,3,3-hexafluoroisopropyl alcohol. The oxidation occurred at similar to 1 V (for [CB11Me12](-)) up to more than 4 V (for [1-H-(2-6)-F-5-(7-12)-(CF3)(6)-CB11](-)) relative to ferrocene/ferricinium. The anodic peak potentials are reproduced by a set of additive position-sensitive substituent increments.
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