期刊
INORGANIC CHEMISTRY
卷 55, 期 19, 页码 9493-9496出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b01113
关键词
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资金
- University of New Hampshire
- Army Research Office [W911NF-14-1-0177]
- NIST [70NANB15H060]
Porphyrin-cored polymer nanoparticles (PCPNs) were synthesized and characterized to investigate their utility as heme protein models. Created using collapsible heme-centered star polymers containing photodimerizable anthracene units, these systems afford model heme cofactors buried within hydrophobic, macromolecular environments. Spectroscopic interrogations demonstrate that PCPNs display redox and ligand-binding reactivity similar to that of native systems and thus are potential candidates for modeling biological heme iron coordination.
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