期刊
INORGANIC CHEMISTRY
卷 55, 期 17, 页码 8564-8569出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.6b01108
关键词
-
资金
- Florida State Univ.
We report precise manipulation of the potential-energy surfaces (PESs) of a series of butterfly-like pyrazolate-bridged platinum binuclear complexes, by synthetic control of the electronic structure of the cyclo-metallating ligand and the steric bulkiness of the pyrazolate bridging ligand. Color tuning of dual emission from blue/red, to green/red and red/deep red were achieved for these phosphorescent molecular butterflies, which have two well-controlled energy minima on the PESs. The environmentally dependent photoluminescence of these molecular butterflies enabled their application as self-referenced luminescent-viscosity sensor.
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