期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 24, 期 2, 页码 1191-1201出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1cp04438a
关键词
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资金
- Departments of Excellence program of the Italian Ministry for Education, University and Research (MIUR, 2018-2022)
A series of new extended linkers containing various polyaromatic chromophores were synthesized through Pd-catalyzed cross-coupling reactions. These linkers exhibited fluorescence in the solid state, making them suitable for the fabrication of fluorescent MOFs.
In this study, a new series of extended linkers containing different polyaromatic chromophores (biphenyl, naphthalene, anthracene, fluorene, 9,9-dimethylfluorene and fluorenone) functionalized with isonicotinoyl moieties have been synthesized by Pd-catalyzed cross-coupling reactions involving isonicotinamide and the appropriate aromatic dibromide. The optimized protocol led to the isolation of the target molecules in good yield and with high purity. These were characterized by H-1 NMR, FTIR, MS, and elemental analysis and their solid state structures were solved by single-crystal X-ray diffraction analysis. Electronic absorption and emission spectra were collected both in solution (DMF) and in the solid state. TDDFT calculations were carried out to investigate the effect of the isonicotinoyl moieties on the spectral features of the central chromophores. Although in solution only the linker containing a fluorenone scaffold shows a weak fluorescence, all the isolated linkers turned out to be fluorescent in the solid state, thus paving the way for their use for the fabrication of fluorescent MOFs.
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