☆ 4.5 Article

Effects of Axial Solvent Coordination to Dirhodium Complexes on the Reactivity and Selectivity in C-H Insertion Reactions: A Computational Study

ORGANOMETALLICS (2021)

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CHEMICAL COMMUNICATIONS (2010)

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A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

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Review Chemistry, Multidisciplinary

Application of donor/acceptor-carbenoids to the synthesis of natural products

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CHEMICAL SOCIETY REVIEWS (2009)

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Combined Experimental and Computational Studies of Heterobimetallic Bi-Rh Paddlewheel Carboxylates as Catalysts for Metal Carbenoid Transformations

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TfNH2 as Achiral Hydrogen-Bond Donor Additive to Enhance the Selectivity of a Transition Metal Catalyzed Reaction. Highly Enantio- and Diastereoselective Rhodium-Catalyzed Cyclopropanation of Alkenes Using α-Cyano Diazoacetamide

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Chemoselective Tryptophan Labeling with Rhodium Carbenoids at Mild pH

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

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Cyclization of Diazoacetamides Catalyzed by N-Heterocyclic Carbene Dirhodium(II) Complexes

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High symmetry dirhodium(II) paddlewheel complexes as chiral catalysts

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Recent excursions to the borderlands between the realms of concerted and stepwise: carbocation cascades in natural products biosynthesis

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JOURNAL OF PHYSICAL ORGANIC CHEMISTRY (2008)

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Catalytic C-H functionalization by metal carbenoid and nitrenoid insertion

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The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: two new functionals and systematic testing of four M06-class functionals and 12 other functionals

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Effect of axial coordination on the electronic structure and biological activity of dirhodium(II,II) complexes

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Review Chemistry, Physical

A new local density functional for main-group thermochemistry, transition metal bonding, thermochemical kinetics, and noncovalent interactions

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Rh(II)-catalyzed intramolecular C-H insertion of diazo substrates in water: Scope and limitations

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Electrophilicity index

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CHEMICAL REVIEWS (2006)

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Universal strategy for the immobilization of chiral dirhodium catalysts

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ORGANIC LETTERS (2005)

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Interactions of metal-metal-bonded antitumor active complexes with DNA fragments and DNA

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Benchmarking the conductor-like polarizable continuum model (CPCM) for aqueous solvation free energies of neutral and ionic organic molecules

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Rh(II) catalysed intramolecular C-H insertion of diazo substrates in water: a simple and efficient approach to catalyst reuse

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Simple strategy for the immobilization of dirhodium tetraprolinate catalysts using a pyridine-linked solid support

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Isotope effects and the nature of selectivity in rhodium-catalyzed cyclopropanations

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Catalytic enantioselective C-H activation by means of metal-carbenoid-induced C-H insertion

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Energies, structures, and electronic properties of molecules in solution with the C-PCM solvation model

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Asymmetric intermolecular C-H activation, using immobilized dirhodium tetrakis((S)-N-(dodecylbenzenesulfonyl)-prolinate) as a recoverable catalyst

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Transition metal-catalyzed cyclopropanation of alkenes in water: Catalyst efficiency and in situ generation of the diazo reagent

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Mechanism of C-H bond activation/C-C bond formation reaction between diazo compound and alkane catalyzed by dirhodium tetracarboxylate

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Catalytic asymmetric cyclopropanation using bridged dirhodium tetraprolinates on solid support

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The first dirhodium tetracarboxylate molecule without axial ligation: New insight into the electronic structures of molecules with importance in catalysis and other reactions

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Rhodium chemzymes: Michaelis-Menten kinetics in dirhodium(II) carboxylate-catalyzed carbenoid reactions

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A stable dirhodium tetracarboxylate carbenoid: Crystal structure, bonding analysis, and catalysis

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Supramolecular arrays based on dimetal building units

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ACCOUNTS OF CHEMICAL RESEARCH (2001)

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Supercritical and liquid solvent effects on the enantioselectivity of asymmetric cyclopropanation with tetrakis[1-[(4-tert-butylphenyl)-sulfonyl]-(2S)-pyrrolidinecarboxylate]dirhodium(II)

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Rhodium-carbenoid-mediated intermolecular O-H insertion reactions: a dramatic additive effect. Application in the synthesis of an ascomycin derivative

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