期刊
ORGANIC PROCESS RESEARCH & DEVELOPMENT
卷 26, 期 3, 页码 480-492出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.oprd.1c00246
关键词
solvent; green chemistry; synthesis; ether; catalysis
资金
- Department of Science and Technology, India (DST, India) [DST/INSPIRE/04/2017/000446]
- ICT-IOCB
The choice of environmentally friendly solvents is crucial for developing sustainable synthetic methodologies. Solvents like 2-MeTHF, CPME, and 4-MeTHP have favorable characteristics that make them promising alternatives to conventional ether solvents, triggering the development of green chemistry protocols in synthetic chemistry.
Solvents are crucial platforms in organic synthesis. Thereby, the choice of a solvent is critical in order to develop sustainable eco-friendly synthetic methodologies. Hence, the present consensus is to employ environmentally friendly solvents which have broad applications in fine chemical syntheses, especially from the context of large-scale industrial preparations. In this review, we provide several examples for the utilization of 2-MeTHF, CPME, and 4-MeTHP in several organic reactions pertaining to organometallic-, organo-, and biocatalysis and highlight their potential use as benign alternatives to conventional ether solvents. These solvents have favorable physical and chemical characteristics, such as low toxicity and high chemical and thermal stabilities, which make them promising media for a large breadth of synthetic chemistry and triggers development of reactions with green chemistry protocols.
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