期刊
ORGANIC LETTERS
卷 24, 期 6, 页码 1400-1404出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.2c00254
关键词
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资金
- National Natural Science Foundation of China [21901071, 21971061]
- Science and Technol-ogy Planning Project of Hunan Province [2018TP1017]
- Science and Technology Innovation Program of Hunan Province [2021RC4059]
A palladium-catalyzed chemoselective decarboxylative annulation of aryl iodides with cyclic beta-bromoacrylic acids is developed for the construction of diverse fused and spiro polycycles. The reaction exhibits high selectivity and diversity by employing different substrates.
A palladium-catalyzed chemoselective decarboxyla-tive annulation of different aryl iodides with cyclic beta-bromoacrylic acids for the construction of interesting fused and spiro polycycles is disclosed. Notably, cyclic beta-bromoacrylic acids can chemo-selectively act as C1 or C2 insertion units by the use of different aryl iodides. 2-Iodo-N-methacryloylbenzamides can undergo a Heck/[4+2] annulation to afford hexahydrodibenzoisoquinoline-4,6(5H)-diones. Employing 2-iodobiphenyls or N-(2-iodophenyl)-2-phenylacrylamides as substrates enables the assembly of spirofluorenes and dispirooxindoles.
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