期刊
ORGANIC LETTERS
卷 24, 期 1, 页码 385-389出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c04060
关键词
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This Letter describes a palladium/copper-cocatalyzed arylsilylation of internal alkynes with acyl fluorides and silylboranes, resulting in tetrasubstituted alkenylsilanes in moderate to good yields. It is the first example of utilizing acyl fluorides for a three-component coupling reaction via decarbonylation.
In this Letter, the palladium/copper-cocatalyzed arylsilylation of internal alkynes with acyl fluorides and silylboranes is described. This is the first example in which acyl fluorides have been utilized for the three-component coupling reaction via decarbonylation, yielding a variety of tetrasubstituted alkenylsilanes in moderate to good yields.
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