4.8 Article

Six-Step Total Synthesis of Isohirsut-4-ene through [5+2+1] Cycloaddition and Transannular Epoxide-Alkene Cyclization

相关参考文献

注意:仅列出部分参考文献,下载原文获取全部文献信息。
Article Chemistry, Multidisciplinary

Mechanism and Stereochemistry of Rhodium-Catalyzed [5+2+1] Cycloaddition of Ene-Vinylcyclopropanes and Carbon Monoxide Revealed by Visual Kinetic Analysis and Quantum Chemical Calculations

Yi Wang et al.

Summary: Through a 15-year investigation, we have delved into the mechanism of the [5 + 2 + 1] cycloaddition, identifying key steps in the catalytic cycle and elucidating the stereochemistry and chemical selectivity of the reaction.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Article Chemistry, Organic

Synthesizing Molecules with Linear Tricyclic 5/5/5 and 6/5/5 Skeletons via [5+2+1]/Ene Strategy

Jing Liu et al.

Summary: The report describes a synthetic strategy for molecules with linear tricyclic 5/5/5 and 6/5/5 skeletons using a [5 + 2 + 1]/ene approach. The strategy involves a Rh-catalyzed [5 + 2 + 1] reaction followed by an InCl3-catalyzed ene reaction to transform the intermediates into the final target molecules, offering an efficient and feasible synthetic route.

ORGANIC LETTERS (2021)

Article Chemistry, Multidisciplinary

Synthesis and Structure Revision of Dichrocephones A and B

Volker M. Schmiedel et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Biochemistry & Molecular Biology

An Improved Scalable Synthesis of α- and β-Amyrin

Immo Serbian et al.

MOLECULES (2018)

Review Chemistry, Multidisciplinary

Tricyclic Sesquiterpenes from Marine Origin

Franck Le Bideau et al.

CHEMICAL REVIEWS (2017)

Article Chemistry, Multidisciplinary

Concise synthesis of (±)-Lingzhiol via epoxy-arene cyclization

Dong Chen et al.

CHEMICAL COMMUNICATIONS (2015)

Article Biotechnology & Applied Microbiology

Novel terpenes generated by heterologous expression of bacterial terpene synthase genes in an engineered Streptomyces host

Yuuki Yamada et al.

JOURNAL OF ANTIBIOTICS (2015)

Article Chemistry, Multidisciplinary

A Systematic Study of Functionalized Oxiranes as Initiating Groups for Cationic Polycyclization Reactions

Goreti Rajendar et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

Article Chemistry, Organic

Total Synthesis of Panaginsene with Structural Revision

Sujeong Geum et al.

ORGANIC LETTERS (2014)

Article Chemistry, Organic

Formal Homoiodo Allylsilane Annulations: Dual Total Syntheses of (±)-Hirsutene and (±)-Capnellene

Shou-Jie Shen et al.

JOURNAL OF ORGANIC CHEMISTRY (2013)

Article Chemistry, Multidisciplinary

Synthesis of highly strained terpenes by non-stop tail-to-head polycyclization

Sergey V. Pronin et al.

NATURE CHEMISTRY (2012)

Article Chemistry, Multidisciplinary

Catalytic, asymmetric transannular aldolizations: Total synthesis of (+)-hirsutene

Carley L. Chandler et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2008)

Article Chemistry, Organic

Rhodium-catalyzed [5+2] cycloaddition reactions in water

PA Wender et al.

SYNLETT (2003)