期刊
ORGANIC LETTERS
卷 24, 期 1, 页码 359-363出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c04029
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资金
- JSPS KAKENHI [JP16H06384, JP20K15954]
The photocatalyzed deoxygenative C-C coupling reaction using xanthate salts as reagents is a promising method for generating alkyl radicals through homolytic cleavage of C-O bonds. The success of this strategy is attributed to the low oxidation potential of xanthate salts and the use of suitable phosphine to accelerate the release of carbonyl sulfide.
The homolytic cleavage of C-O bonds to afford alkyl radicals is an attractive yet challenging transformation in organic synthesis. Herein we describe a photocatalyzed deoxygenative C-C coupling reaction of xanthate salts, which can be easily prepared from the corresponding alcohols. The key to the success of this strategy is the low oxidation potential of the xanthate salt and the use of an appropriate phosphine to accelerate the desulfurative release of carbonyl sulfide.
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