期刊
ORGANIC LETTERS
卷 24, 期 3, 页码 924-928出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c04293
关键词
-
资金
- National Natural Science Foundation of China [22078370, 21776318, 22078369, 22003077]
- Basic Science Center Project for National Natural Science Foundation of China [72088101]
- Natural Science Foundation of Hunan Province [2018JJ3868, 2020JJ4682]
- Central South University
- Open Research Fund of School of Chemistry and Chemical Engineering, Henan Normal University
We describe a highly modular 1,4-difunctionalization of 1,3-dienes with bromodifluoroacetamides and sulfinates/amines through a photoinduced palladium-catalyzed radical relay process. This protocol offers a facile and general route to access a variety of value-added CF2-incorporated alkenes in moderate to good yields. The versatility and flexibility of this approach have been well demonstrated by readily accessible starting materials, synthetic convenience, and wide functional group compatibility.
A highly modular 1,4-difunctionalization of 1,3-dienes with bromodifluoroacetamides and sulfinates/amines through a photoinduced palladium-catalyzed radical relay process is described herein. This developed protocol offers a facile and general route to access a variety of value-added CF2-incorporated alkenes in moderate to good yields. The versatility and flexibility of this approach have been well illustrated by readily accessible starting materials, synthetic convenience, and wide functional group compatibility.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据