期刊
ORGANIC LETTERS
卷 24, 期 3, 页码 924-928出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c04293
关键词
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资金
- National Natural Science Foundation of China [22078370, 21776318, 22078369, 22003077]
- Basic Science Center Project for National Natural Science Foundation of China [72088101]
- Natural Science Foundation of Hunan Province [2018JJ3868, 2020JJ4682]
- Central South University
- Open Research Fund of School of Chemistry and Chemical Engineering, Henan Normal University
We describe a highly modular 1,4-difunctionalization of 1,3-dienes with bromodifluoroacetamides and sulfinates/amines through a photoinduced palladium-catalyzed radical relay process. This protocol offers a facile and general route to access a variety of value-added CF2-incorporated alkenes in moderate to good yields. The versatility and flexibility of this approach have been well demonstrated by readily accessible starting materials, synthetic convenience, and wide functional group compatibility.
A highly modular 1,4-difunctionalization of 1,3-dienes with bromodifluoroacetamides and sulfinates/amines through a photoinduced palladium-catalyzed radical relay process is described herein. This developed protocol offers a facile and general route to access a variety of value-added CF2-incorporated alkenes in moderate to good yields. The versatility and flexibility of this approach have been well illustrated by readily accessible starting materials, synthetic convenience, and wide functional group compatibility.
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