Uracil-mediated supramolecular assembly for C-enriched porous carbon nitrides with enhanced photocatalytic hydrogen evolution

The substitution of C for N in graphitic carbon nitride (g-C3N4) can promote pi-electron availability and increase photocatalytic activity, but the low specific surface area still limits its performance. Herein, porous C-doped g-C3N4 was prepared by the uracil-mediated supramolecular assembly of melamine and cyanuric acid. The as-prepared catalyst exhibited a high photocatalytic hydrogen evolution rate of 2352 mu mol g(-1) h(-1) under visible light irradiation (lambda >= 420 nm), which was 28 times that of g-C3N4 (83 mu mol g(-1) h(-1)), due to the porous architecture and C-doping effect. The porous architecture endowed the catalyst with a large specific surface area (79.4 m(2) g(-1)) and great light utilization efficiency in the visible light region between 500 and 750 nm. In addition, C-doping modified the energy band structure of g-C3N4 to a narrow band gap (from 2.92 eV to 2.78 eV) and enhanced the separation efficiency of photogenerated carriers.

Automated summary

Porous C-doped g-C3N4 with large specific surface area and high light utilization efficiency was prepared using uracil-mediated supramolecular assembly. C-doping modified the energy band structure of g-C3N4, leading to enhanced separation efficiency of photogenerated carriers and significantly improved photocatalytic activity.