期刊
NEW JOURNAL OF CHEMISTRY
卷 46, 期 3, 页码 945-949出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1nj05433c
关键词
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资金
- National Key Research and Development Program of China [2016YFB0401400]
- National Natural Science Foundation of China [22071129, 21871158]
- Department of Education of Guangdong Province [2016KCXTD005]
- Youth Foundation of Wuyi University [2017td01]
A [2 + 2 + 1] annulation protocol has been developed for the modular synthesis of 2,4-disubstituted thiophenes/selenophenes, showing excellent regioselectivity. Catalyzed by copper salt, the reactions utilize elemental sulfur and selenium as the chalcogen source. Mechanistic studies indicate that the process is initiated by a trisulfur radical anion detected using EPR.
A [2 + 2 + 1] annulation protocol has been established for the modular synthesis of 2,4-disubstituted thiophenes/selenophenes, with excellent regioselectivity. The reactions have been catalyzed by copper salt with elemental sulfur and selenium serving as the chalcogen source. The mechanistic study has revealed that this process was initiated by a trisulfur radical anion using EPR.
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