期刊
NEW JOURNAL OF CHEMISTRY
卷 46, 期 4, 页码 1791-1799出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/d1nj05411b
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资金
- National Natural Science Foundation of China [NSF22061038, 22067018]
- Natural Science Foundation of Gansu [20JR5RA042]
- Innovation Ability Promotion Project of Colleges and Universities in Gansu Province [2021A-241]
- Qinghai University Young and Middle-aged Research Fund Project [KJQN2021008]
N-doped porous carbon synthesized from sugar cane bagasse exhibited superior catalytic performance in the aerobic dehydrogenation of various heterocyclic nitrogen compounds, attributed to its high activation ability for both O-2 and heterocyclic nitrogen due to its porous structure and pyridinic N species.
N-doped porous carbon (NC) was synthesized from sugar cane bagasse, which is a sustainable and widely available biomass waste. The preferred NC sample had a well-developed porous structure, a graphene-like surface morphology and different N species. More importantly, the heterogeneous carbocatalyst exhibited superior catalytic performance in the aerobic dehydrogenation of various heterocyclic nitrogen compounds (49 examples, up to 96% yield), similar to that of C3N4 and GO. Characterization by TEM, BET and XPS accompanied by the EPR analysis revealed that the enhanced catalytic properties of NC came from its high activation ability for both O-2 and heterocyclic nitrogen, attributed to the porous structure and pyridinic N (N-6) species, respectively.
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