The synergistic effect of CuBi2O4 and Co-Pi: improving the PEC activity of BiVO4-based composite materials

Reducing the reaction barrier on the photoelectrode surface and increasing the water oxidation power of the sample surface are the key issues to improve photoelectrochemical water splitting performances. In this study, a new BiVO4/CuBi2O4/Co-Pi photoanode has been prepared. CuBi2O4 and BiVO4 form a heterojunction structure that widens the absorption range of light and accelerates the separation of photogenerated carriers in the photoanode, thereby allowing holes into the next layer (cocatalyst layer) faster. The Co-Pi constituent acts as a water oxidation catalyst that can accelerate the interface charge transfer and increase the active surface area. Linear sweep voltammetry is used to determine the photocurrent density of BiVO4/CuBi2O4/Co-Pi, being 1.88 and 1.23 times bigger than that of BiVO4 and BiVO4/CuBi2O4, respectively. In addition to this, the BiVO4/CuBi2O4/Co-Pi photoanode creates a synergy effect that leads to a wider range of light absorption, higher carrier separation efficiency, and greater water oxidation power so the hydrogen evolution and oxygen evolution rates after recombination increased by 5.68 times and 5.66 times. The results prove that ternary semiconductor structures can improve photoelectrochemical performance. The strategy has great potential in the development of photoelectrochemical water splitting.

Automated summary

In this study, a BiVO4/CuBi2O4/Co-Pi photoanode was prepared to enhance the photoelectrochemical water splitting performances. It was found that the heterojunction structure of CuBi2O4 and BiVO4 widened the absorption range of light and accelerated the separation of photogenerated carriers. The presence of Co-Pi constituent as a water oxidation catalyst further improved the interface charge transfer and increased the active surface area. The results showed that the ternary semiconductor structure can greatly enhance photoelectrochemical performance, making it a promising strategy for the development of photoelectrochemical water splitting.