4.3 Article

Oxygenated Sesquiterpenes From the Indo-Pacific Nudibranch Ardeadoris rubroannulata: Structure Revision of Pu'ulenal

期刊

NATURAL PRODUCT COMMUNICATIONS
卷 16, 期 10, 页码 -

出版社

SAGE PUBLICATIONS INC
DOI: 10.1177/1934578X211055025

关键词

Ardeadoris rubroannulata; sesquiterpene; terpenoid; NMR; x-ray crystallography; DFT; absolute configuration

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  1. School of Chemistry and Molecular Biosciences
  2. University of Queensland

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Seven oxygenated sesquiterpenes were isolated from an organic extract of the nudibranch Ardeadoris rubroannulata collected from Eastern Australia. The structure of pu'ulenal 2 was revised to a 9Z configuration, while isopu'ulenal 3 was found to have the 9E configuration previously attributed to pu'ulenal.
Seven oxygenated sesquiterpenes 1 to 7 each with a drimane framework were isolated from an organic extract of the nudibranch Ardeadoris rubroannulata collected from Eastern Australia. The structure of pu'ulenal 2 was revised by 1D NOESY, providing a 9Z configuration, while isopu'ulenal 3 has the 9E configuration previously ascribed to pu'ulenal.

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