期刊
INDUSTRIAL CROPS AND PRODUCTS
卷 83, 期 -, 页码 155-165出版社
ELSEVIER
DOI: 10.1016/j.indcrop.2015.12.048
关键词
Organosolv; Kraft; Functional groups; Proximate analysis; Lignin methacrylates
资金
- University of the Basque Country [PIF 13/050]
- Spanish Ministry of Economy and Competitiveness [CTQ2013-41246-R]
- Knut and Alice Wallenberg Foundation
- Wallenberg Wood Science Center (WWSC)
The potential of organosolv and kraft eucalyptus and spruce lignin as feedstock for polymeric materials and biofuel applications was assessed. Proximate analysis was used to predict the heating values and char formation. Chemical modification, based on the esterification reaction with methacryloyl chloride, was applied to introduce vinyl groups into the lignin macromolecules for enhanced reactivity. Kraft eucalyptus and spruce lignins had a more condensed structure than organosolv lignins, which resulted in greater thermal stability for these lignins. For different species within the same process, the thermal parameters showed a correlation with certain structural and compositional parameters (ash and sugars content, molecular weight and degree of condensation). Organosolv spruce lignin produced the highest heating value of 24MJ/Kg, which is suitable for biofuel applications. The content of phenolic OH groups was higher for kraft lignins and especially higher for softwood lignins, both organosolv and kraft. The degree of methacrylation, estimated from the content of vinyl groups per C9 lignin unit, was significantly greater for organosolv lignins than for kraft lignins despite the higher OH-groups content in the latter. (c) 2015 Elsevier B.V. All rights reserved.
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