期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 334, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.micromeso.2022.111764
关键词
ZrO2 membrane; Ceramic membrane; Co-sintering; Sol separation
类别
资金
- National Key Research and Development Program of China [2021YFC2101205]
- National Natural Science Foundation of China [22078147, 21921006]
- National High Technical Research and Development Program of China [2012AA03A606]
- Research Project of National Synthetic Biotechnology Innovation Centre [TSBICIP-KJGG-002-16]
- PAPD
- Project for Marine17 Science and Technology Innovation of Jiangsu Province [HY2018-10]
A co-sintering technique is used to fabricate ZrO2 dual-layer ceramic mesoporous membranes with high separation precision and water permeance. The thickness of the sublayer can be controlled to adjust the permeance, and co-sintering reduces the fabrication cost and time. Additionally, the membrane has a high rejection rate towards SiO2 nanoparticles.
The application of ceramic mesoporous membranes is mainly limited by the trade-off between separation performance and fabrication cost. Here, a co-sintering technique is employed to fabricate ZrO2 dual-layer ceramic mesoporous membranes with high separation precision and water permeance. Based on a coarse ceramic substrate, dual layers that could effectively decrease the fabrication cost and time were co-sintered. By doping zirconia nanoparticles in the sublayer, the sintering temperature could be decreased, and a high bonding strength was achieved between the dual layers. It is demonstrated that the permeance can be finely tuned by controlling the thickness of the sublayer. The resulting membrane exhibited a high water permeance of 280 L m(-2) h(-1) bar(-1) and a molecular weight cut-off of 40-50 kDa. The zirconia mesoporous membrane was employed for sol separation, affording a 100% rejection rate toward SiO2 nanoparticles. The cost-effective ZrO2 mesoporous membrane exhibits significant application potential for the separation of industrial SiO2 sols.
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