Cr-doped UiO-66 with enhanced water adsorption for adsorption heat transformation

In this study, the possible applications of Cr-doped UiO-66 in adsorption heat transformation (AHT) were investigated. Four different Cr-doped UiO-66 samples were prepared to examine their structures and water adsorption properties. Results showed that Cr-doped UiO-66 samples have higher pore volume and specific surface area than pure UiO-66 samples. In particular, 0.2Cr-UiO-66 has the highest BET specific surface area (993 m2/g) and micropore volume (0.50 cm3/g), which are 31.6% and 29.6% higher than those of unmodified UiO-66, respectively. Water adsorption tests revealed that Cr doping can improve the water adsorption performances of UiO-66. At 25 degrees C and P/P0 = 0.9, the saturated water uptake of 1.0Cr-UiO-66 is 0.69 g/g, which is 64.3% higher than that of pure UiO-66. After 10 adsorption/desorption cycles, the water adsorption capacity of pure UiO-66 and 0.5Cr-UiO-66 samples has decreased by 3.4% and 5.7%, respectively, indicating their good cycle stability. All these results indicate that Cr doping is beneficial to UiO-66 application in AHT.

Automated summary

This study investigates the potential applications of Cr-doped UiO-66 in adsorption heat transformation (AHT). The results show that Cr-doped UiO-66 samples have higher pore volume and specific surface area compared to pure UiO-66 samples, with the 0.2Cr-UiO-66 sample exhibiting the highest BET specific surface area and micropore volume. Water adsorption tests demonstrate that Cr doping enhances the water adsorption performances of UiO-66. The water uptake of 1.0Cr-UiO-66 is 64.3% higher than that of pure UiO-66, and both pure UiO-66 and 0.5Cr-UiO-66 samples exhibit good cycle stability.