期刊
MICROPOROUS AND MESOPOROUS MATERIALS
卷 331, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.micromeso.2021.111619
关键词
Nanocomposites; Dendrimeric silica; In-situ catalyst supporting; Polyethylene; Mechanical response
类别
资金
- Fundacao para a Ciencia e Tecnologia (FCT)
- CQE-FCT 55 [UIDB/00100/2020]
- FCT-CATSUS program
- PAUILF [TC 04/17]
- FCT [PD/BD/114580/2016]
- Agencia Estatal de Investigacion (AEI, Spain)
- European Regional Development Fund (FEDER, UE) [MAT2016-79869-C2-1-P]
- CSIC [2020AEP129]
- Fundação para a Ciência e a Tecnologia [PD/BD/114580/2016] Funding Source: FCT
Materials prepared using the DS-SA method exhibit superior filler dispersion and significantly higher mechanical performance at high filler loadings compared to their DS-MAO counterparts, while still retaining the ultimate stretching ability of HDPE.
A set of dendrimeric silica (DS) reinforced polyethylene-based nanocomposites is prepared using a novel and straightforward in-situ catalyst supporting procedure by means of in-situ polymerization technique, labeled DSSA. These materials are characterized with regard to molar masses, filler dispersion, thermal stability, crystalline characteristics, thermal properties and mechanical response and then compared with an equivalent set of samples prepared using a more common method, named DS-MAO, as well as a non-reinforced HDPE reference. The mechanical performance of all these materials is discussed based on the crystalline features and molar masses of the polymeric component together with the dispersion of the DS nanofiller. The results of this study confirm the potential of the DS-SA approach as an innovative and promising technique, with resulting materials achieving superior filler dispersion and significantly higher mechanical performance compared to their DS-MAO analogues at high filler loadings, while retaining the limit stretching ability of HDPE.
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