4.6 Article

Utilization of MoS2 Nanosheets To Enhance the Photocatalytic Activity of ZnO for the Aerobic Oxidation of Benzyl Halides under Visible Light

期刊

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
卷 55, 期 32, 页码 8726-8732

出版社

AMER CHEMICAL SOC
DOI: 10.1021/acs.iecr.6b01420

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资金

  1. National Natural Science Funds for Excellent Young Scholars [21222608]
  2. Foundation for the Author of National Excellent Doctoral Dissertation of China [201251]
  3. Program for New Century Excellent Talents in University [NCET-12-0392]
  4. Program of Introducing Talents of Discipline to Universities [B06006]

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Semiconductors are the low cost and recyclable photo catalysts for visible-light photoredox catalysis, which is one of the prospective ways to convert solar energy to chemical energy in organic synthesis. This study reports a new MoS2/ZnO composite for the aerobic oxidation of benzyl halides under visible light. Despite the limited intrinsic activity of the ZnO alone, we found that the introduction of a small amount of MoS2 nanosheets (4 wt %) could significantly improve the catalytic performances of the ZnO in visible-light photoredox catalysis.

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