期刊
出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.msea.2021.142353
关键词
Cu-Cr-Zr-Si alloy; Grain refinement; Phase evolution; Thermodynamic calculations; First principles; Mechanical properties
类别
资金
- National Key Research and Develop-ment Program of China [2018YFE0306103, 2017YFB0306105]
- National Natural Science Foundation of China [51771040, 51690163, 51525401]
- science and technology innovation project of Ningbo [2018B10030]
The study investigated the impact of Si content on the microstructure evolution and properties of CuCr0.8Zr0.12Six alloys through thermodynamic analysis and first-principles calculation, revealing a direct relationship between the Si content, mechanical properties, and the formation of Cr3Si. Experimentally, it was found that CuCr0.8Zr0.12Si0.05 exhibited the highest comprehensive properties with increased tensile strength, elongation, electrical conductivity, and hardness compared to other Si content levels within the range of 0 to 0.2 wt%.
The CuCr0.8Zr0.12Six (wt.%, x = 0, 0.02, 0.05 and 0.2) alloys were designed and prepared by casting method. The function mechanism of Si content on as-cast microstructure evolution and properties was revealed with the guidance of thermodynamic analysis and first-principles calculation. Cr3Si tends to form during solidification at higher Si content due to its relatively low excess Gibbs free energy, which was proven to significantly affect the mechanical properties of alloys. The relationship between microstructure and mechanical properties of as-cast CuCr0.8Zr0.12Six alloy was also experimentally investigated. With Si content increasing from 0 to 0.2 wt%, the tensile strength and elongation of the CuCr0.8Zr0.12Six alloys simultaneously increase from 251 MPa to 29.0% in CuCr0.8Zr0.12Si0 to 268 MPa and 33.0% in CuCr0.8Zr0.12Si0.05, and then decrease to 229 MPa and 23.7% in CuCr0.8Zr0.12Si0.2. Simultaneously, the electrical conductivity and hardness of CuCr0.8Zr0.12Si0.05 respectively reach 57.2 %IACS and 85.1 HV, CuCr0.8Zr0.12Si0.05 was thus identified to be the best composition with relatively high comprehensive properties in this case.
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