期刊
MATERIALS LETTERS
卷 305, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.matlet.2021.130843
关键词
Pd-Ga/Al2O3; Palladium catalyst; Pd2Ga; Acetylene hydrogenation
资金
- Ministry of Science and Higher Education of the Russian Federation [AAAA-A21-121011390011-4]
The study explores how modifying the electronic properties of palladium by gallium and forming bimetallic Pd2Ga particles can increase the selectivity of ethylene.
The structural properties of Pd-Ga/gamma-Al2O3 samples prepared from joint Pd(NO3)(2) and Ga(NO3)(3) solution and their catalytic properties in liquid-phase acetylene hydrogenation have been studied. Using temperature programmed reduction (TPR-H-2), transmission electron microscopy (TEM), diffuse reflectance infrared Fourier transform spectroscopy of adsorbed CO (CO-DRIFTS) and X-ray photoelectron spectroscopy (XPS) it was found that an increase in the ethylene selectivity to similar to 66-70% is explained by the modification of the electronic properties of palladium by gallium at a Ga:Pd molar ratio of 0.5 and by the formation of bimetallic Pd2Ga particles in the case of Ga:Pd = 2.
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