4.4 Article

Ethylene/Propylene/Diene Terpolymers Grafted with Poly(methyl acrylate) by Reverse Atom Transfer Radical Polymerization

期刊

MACROMOLECULAR CHEMISTRY AND PHYSICS
卷 222, 期 22, 页码 -

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/macp.202100189

关键词

graft copolymers; ATRP; reverse ATRP; polymer flocculants; polyolefins

资金

  1. Campus Alberta Innovates Program
  2. NSERC
  3. IOSI
  4. COSIA

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This study describes the synthesis of ethylene-propylene-diene terpolymers grafted with poly(methyl acrylate) (PMA) by reverse atom transfer radical polymerization, with the molecular weights and densities of PMA grafts being controlled by various factors. The grafted copolymers are characterized by different spectroscopic techniques, and copolymers with a range of graft molecular weights and densities are successfully prepared using this method.
This article describes the synthesis of ethylene-propylene-diene terpolymers grafted with poly(methyl acrylate) (PMA) by reverse atom transfer radical polymerization. The PMA graft molecular weights and densities are controlled by varying the concentration and conversion of methyl acrylate, as well as the concentration of initiator. The grafted copolymers are characterized by Fourier-transform infrared spectroscopy, proton NMR, and gel permeation chromatography. Copolymers with graft molecular weights varying from 12 to 179 kDa and grafting densities from 11% to 53% are made following this procedure.

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