期刊
JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
卷 129, 期 -, 页码 342-349出版社
ELSEVIER
DOI: 10.1016/j.jtice.2021.09.026
关键词
Leaf extract; Corrosion inhibitor; Polarization; Impedance; Surface analysis
资金
- Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq) [001]
- Fundacao de Amparoa Pesquisa e Inovacao do Estado de Santa Catarina (FAPESC)
The study on the efficiency of Syzygium cumini leaf extract as a corrosion inhibitor for carbon steel in sulfuric acid medium showed that increasing concentration of leaf extract can decrease corrosion rate and enhance inhibition efficiency by blocking active corroding sites.
The efficiency of Syzygium cumini leaf extract (SCLE) as a corrosion inhibitor was evaluated for carbon steel in 0.5 mol L-1 H2SO4 by potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS) measurements. It was clearly demonstrated that the inhibition efficiency increased with increasing concentration of leaf extract, due to a decrease in the cathodic currents and blocking of the active corroding sites. The presence of organic molecules from the SCLE on the carbon steel surface was confirmed by FT-IR spectroscopy. The adsorption of species on the alloy surface was modeled using the Langmuir isotherm. A decrease in the carbon steel acid corrosion in the presence of SCLE was also confirmed through contact angle measurements and scanning electron microscopy (SEM). (c) 2021 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserved.
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