期刊
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
卷 169, 期 2, 页码 -出版社
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1945-7111/ac4b85
关键词
Thermal encapsulation; Aqueous zinc battery; Ferrocene; Green synthesis; Organic cathode
资金
- Science and Engineering Research Board, DST India [EMR/2016/00l977]
- CSIR institute project funding [MLP-00320]
This study reports a ferrocene-based organic cathode synthesized following green chemistry principles and stabilized by low-temperature thermal encapsulation in multiwalled carbon nanotubes. The intercalation improves the capacity and retention of the electrode material, and the stability is attributed to the friendly host-guest interaction between CNTs and organic molecules. The thermal intercalation in MWCNTs is found to be an excellent method for stabilizing electrode materials in battery applications.
Aqueous zinc batteries are increasingly gaining attention of the researchers in recent years because of their environmental and user friendliness as well as the economic benefits of the zinc metal. Herein we report a ferrocene based organic cathode synthesized by following green chemistry principle and stabilized by low temperature thermal encapsulation in multiwalled carbon nano tubes (MWCNTs) for stable electrochemical performance. Successful intercalation was confirmed by XRD, Raman, FTIR spectra, TEM-HAADF imaging. Without encapsulation, material exhibited initial capacity of 64.7 mAhg(-1) which was drastically faded with time due to dissolution of active material. However, by low temperature thermal encapsulation, the capacity was remarkably improved to 71.3 mAhg(-1) with 94% columbic efficiency and 91% capacity retention at a current density of 75 mAg(-1) in a 100 charge/discharge cycles. The stability of the electrode has been explained on the basis of a friendly host-guest interaction between CNTs and the organic molecules by pi-pi stacking, dipole-dipole and dipole induced dipole interactions with detailed electrochemical and spectroscopic characterization. From this study we conclude that the thermal intercalation in MWCNTs has been found to be excellent method to stabilize the electrode materials in battery application.
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