Loading Impact of a PGM-Free Catalyst on the Mass Activity in Proton Exchange Membrane Fuel Cells

Platinum-group-metal-free (PGM-free) catalysts are currently considered as potential oxygen-reduction-reaction (ORR) catalysts to replace costly and supply-limited platinum at the cathode side of proton exchange membrane fuel cells (PEMFCs). Extensive research efforts have led to substantial progress with regards to the ORR activity of PGM-free ORR catalysts, but there is uncertainty about the dependence of the mass activity on the catalyst loading. In this study, the effect of catalyst loading on the mass activity is investigated by means of rotating disk electrode measurements as well as single cell PEMFC tests using a commercial PGM-free ORR catalyst. Single cell tests with a wide range of loadings (0.4-4.0 mg(cat) cm(-2) (MEA)) are compared to rotating disk electrode measurements with low loadings of 40-600 mu g(cat) cm(-2) (disk). In contrast to indications in the literature that the ORR activity depends on catalyst loading, our results reveal an independence of the ORR mass activity from the catalysts loading in both RDE and PEMFC tests, if corrections for the voltage losses in H-2/O-2 single cell tests are considered. Moreover, no clear relation of the stability to the catalyst loading was found in H-2/O-2 PEMFCs.

Automated summary

This study investigated the impact of catalyst loading on the mass activity of PGM-free ORR catalysts, revealing an independence of the ORR mass activity from the catalysts loading when corrections for voltage losses in H-2/O-2 single cell tests are considered. Additionally, no clear relation of stability to the catalyst loading was found in H-2/O-2 PEMFCs.