☆ 4.8 Article

Photoinduced Copper-Catalyzed Asymmetric Acylation of Allylic Phosphates with Acylsilanes

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Review Chemistry, Multidisciplinary

Chiral Photocatalyst Structures in Asymmetric Photochemical Synthesis

Matthew J. Genzink et al.

Summary: Asymmetric photocatalysis is a major research topic in contemporary synthetic organic chemistry. However, the discovery of general strategies for highly enantioselective photochemical reactions has been a recent development, leading to a somewhat limited variety of stereocontrolled photoreactions. This review summarizes the chiral catalyst structures that have been studied for solution-phase asymmetric photochemistry, providing insight into the logic required for highly effective stereocontrolled photocatalysis.

CHEMICAL REVIEWS (2022)

添加到收藏夹

Review Chemistry, Multidisciplinary

Stereoinduction in Metallaphotoredox Catalysis

Alexander Lipp et al.

Summary: Metallaphotoredox catalysis has become a crucial platform for constructing C(sp(3))-hybridized centers under mild conditions. Recent research has focused on understanding stereoinduction in dual catalytic processes, with Ni and Cu-catalyzed transformations playing a predominant role. Enantioselective bond formations enabled by Ni and Cu-catalysis have seen significant progress, along with discussions on stereochemical control in diastereoselective transformations.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Quaternary stereocentres via catalytic enantioconvergent nucleophilic substitution reactions of tertiary alkyl halides

Zhaobin Wang et al.

Summary: The development of efficient methods, particularly catalytic and enantioselective processes, for the construction of all-carbon quaternary stereocentres is an important and difficult challenge in organic synthesis. A nickel-based chiral catalyst has been shown to achieve enantioconvergent couplings of tertiary electrophiles with alkenylmetal nucleophiles, providing access to a variety of organic compounds with good yield and enantioselectivity. This approach offers a potentially versatile strategy for the synthesis of complex molecules, including natural product intermediates.

NATURE CHEMISTRY (2021)

添加到收藏夹

Review Chemistry, Multidisciplinary

Enantioselective Formation of Quaternary Centers by Allylic Alkylation with First-Row Transition-Metal Catalysts

Lars Susse et al.

Summary: Asymmetric allylic alkylation using transition metals offers an efficient strategy for generating quaternary stereocenters. Recent advancements have shown the potential of first-row transition metals as a cost-effective and potentially equally efficient alternative. This review highlights the use of different transition metals for catalyzing reactions with nucleophiles to assemble quaternary stereocenters.

CHEMICAL REVIEWS (2021)

添加到收藏夹

Article Chemistry, Organic

Visible-Light-Induced In Situ Generation of Fischer-Type Copper Carbene Complexes from Acylsilanes and Its Application to Catalytic [4+1] Cycloaddition with Siloxydienes

Taiichi Takeuchi et al.

Summary: A novel methodology was developed for in situ generation of Fischer-type metal-carbene complexes, where a catalytic amount of copper was used to form a Fischer-type copper-siloxycarbene complex intermediate.

ORGANIC LETTERS (2021)

添加到收藏夹

Article Chemistry, Organic

Visible-Light-Induced Catalyst-Free Carboxylation of Acylsilanes with Carbon Dioxide

Zhengning Fan et al.

Summary: Intermolecular carbon-carbon bond formation between acylsilanes and carbon dioxide was achieved through photoirradiation without a catalyst. Siloxycarbenes generated from acylsilanes added to the C=O bond of CO2, leading to the synthesis of alpha-ketocarboxylic derivatives. Control experiments show that the siloxycarbene likely comes from the singlet state of the acylsilane and the addition to CO2 is not concerted.

ORGANIC LETTERS (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Photoinduced Copper-Catalyzed Asymmetric C-O Cross-Coupling

Jun Chen et al.

Summary: This study presents a photoinduced copper-catalyzed cross-coupling reaction for the generation of allylic esters. The reaction proceeds at room temperature with high regio- and enantioselectivity.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Visible Light Induced Cu-Catalyzed Asymmetric C(sp3)-H Alkylation

Rupeng Qi et al.

Summary: Asymmetric functionalization of C-H is a attractive strategy in asymmetric synthesis, and photoredox catalysis has emerged as an efficient way to synthesize organic compounds under mild conditions.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Catalytic asymmetric C-C cross-couplings enabled by photoexcitation

Giacomo E. M. Crisenza et al.

Summary: Enantioselective catalytic processes can be achieved by using visible light to alter the reactivity of chiral iridium complexes, enabling new mechanistic pathways. Photoexcitation induces a redox event that unlocks difficult-to-realize reactions, such as enantioselective alkyl-alkyl cross-coupling between allylic alcohols and radical precursors.

NATURE CHEMISTRY (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Efficient Generation and Synthetic Applications of Alkyl-Substituted Siloxycarbenes: Suppression of Norrish-Type Fragmentations of Alkanoylsilanes by Triplet Energy Transfer

Kento Ishida et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

添加到收藏夹

Article Chemistry, Organic

Copper-Catalyzed Photoinduced Enantioselective Dual Carbofunctionalization of Alkenes

Yajing Zhang et al.

ORGANIC LETTERS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Photoinduced Copper-Catalyzed Asymmetric Decarboxylative Alkynylation with Terminal Alkynes

Hai-Dong Xia et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Review Chemistry, Physical

Transition Metal-Catalyzed Organic Reactions under Visible Light: Recent Developments and Future Perspectives

Wan-Min Cheng et al.

ACS CATALYSIS (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Streamlined Catalytic Enantioselective Synthesis of α-Substituted β,γ-Unsaturated Ketones and Either of the Corresponding Tertiary Homoallylic Alcohol Diastereomers

Juan del Pozo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Catalytic enantioselective allene-anhydride approach to β,γ-unsaturated enones bearing an α-all-carbon-quarternary center

Yuan Yuan et al.

CHEMICAL SCIENCE (2020)

添加到收藏夹

Review Multidisciplinary Sciences

ORGANIC CHEMISTRY Copper's rapid ascent in visible-light photoredox catalysis

Asik Hossain et al.

SCIENCE (2019)

添加到收藏夹

Article Chemistry, Physical

Dual-Functional Chiral Cu-Catalyst-Induced Photoredox Asymmetric Cyanofluoroalkylation of Alkenes

Quanping Guo et al.

ACS CATALYSIS (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Copper-Catalyzed Enantioselective Allylboration of Alkynes: Synthesis of Highly Versatile Multifunctional Building Blocks

Eva Rivera-Chao et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Visible-Light-Induced, Metal-Free Carbene Insertion into B-H Bonds between Acylsilanes and Pinacolborane

Jian-Heng Ye et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

添加到收藏夹

Review Chemistry, Multidisciplinary

Catalysis with Palladium Complexes Photoexcited by Visible Light

Padon Chuentragool et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

添加到收藏夹

Review Chemistry, Multidisciplinary

Asymmetric Photocatalysis with Bis-cyclometalated Rhodium Complexes

Xiaoqiang Huang et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

添加到收藏夹

Review Chemistry, Physical

Photoredox catalysts based on earth-abundant metal complexes

Bryony M. Hockin et al.

CATALYSIS SCIENCE & TECHNOLOGY (2019)

添加到收藏夹

Article Chemistry, Multidisciplinary

Enantioselective and site-specific copper-catalyzed reductive allyl-allyl cross-coupling of allenes

Guoxing Xu et al.

CHEMICAL SCIENCE (2019)

添加到收藏夹

Review Chemistry, Organic

Advances in asymmetric visible-light photocatalysis, 2015-2019

Chunhui Jiang et al.

ORGANIC & BIOMOLECULAR CHEMISTRY (2019)

添加到收藏夹

Review Chemistry, Multidisciplinary

Visible-Light Photocatalysis: Does It Make a Difference in Organic Synthesis?

Leyre Marzo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Lewis Acid-Assisted Photoinduced Intermolecular Coupling between Acylsilanes and Aldehydes: A Formal Cross Benzoin-Type Condensation

Kento Ishida et al.

CHEMISTRY-A EUROPEAN JOURNAL (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Synthesis of α-Quaternary Formimides and Aldehydes through Umpolung Asymmetric Copper Catalysis with Isocyanides

Kentaro Hojoh et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Review Chemistry, Multidisciplinary

Visible light-induced transition metal-catalyzed transformations: beyond conventional photosensitizers

Marvin Parasram et al.

CHEMICAL SOCIETY REVIEWS (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Construction of Quaternary Stereogenic Carbon Centers through Copper-Catalyzed Enantioselective Allylic Alkylation of Azoles

Hirohisa Ohmiya et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

添加到收藏夹

Article Chemistry, Multidisciplinary

Copper-Catalyzed Enantioselective Allyl-Allyl Coupling between Allylic Boronates and Phosphates with a Phenol/N-Heterocyclic Carbene Chiral Ligand

Yuto Yasuda et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

添加到收藏夹

Review Chemistry, Multidisciplinary

Organic Photoredox Catalysis

Nathan A. Romero et al.

CHEMICAL REVIEWS (2016)

添加到收藏夹

Article Chemistry, Organic

Photoredox Catalysis in Organic Chemistry

Megan H. Shaw et al.

JOURNAL OF ORGANIC CHEMISTRY (2016)

添加到收藏夹

Article Chemistry, Organic

1,3-Dithianes as Acyl Anion Equivalents in Pd-Catalyzed Asymmetric Allylic Substitution

Kun Yao et al.

ORGANIC LETTERS (2016)

添加到收藏夹

Article Multidisciplinary Sciences

Asymmetric copper-catalyzed C-N cross-couplings induced by visible light

Quirin M. Kainz et al.

SCIENCE (2016)

添加到收藏夹

Review Chemistry, Multidisciplinary

Enantioselective Catalysis of Photochemical Reactions

Richard Brimioulle et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

N-Heterocyclic Carbene-Copper-Catalyzed Group-, Site-, and Enantioselective Allylic Substitution with a Readily Accessible Propargyl(pinacolato)boron Reagent: Utility in Stereoselective Synthesis and Mechanistic Attributes

Ying Shi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Stereospecific Rhodium-Catalyzed Allylic Substitution with Alkenyl Cyanohydrin Pronucleophiles: Construction of Acyclic Quaternary Substituted α,β-Unsaturated Ketones

Ben W. H. Turnbull et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Formaldehyde N,N-Dialkylhydrazones as Neutral Formyl Anion Equivalents in Iridium-Catalyzed Asymmetric Allylic Substitution

Simon Breitler et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

添加到收藏夹

Review Chemistry, Multidisciplinary

Carbonylation Reactions of Alkyl Iodides through the Interplay of Carbon Radicals and Pd Catalysts

Shuhei Sumino et al.

ACCOUNTS OF CHEMICAL RESEARCH (2014)

添加到收藏夹

Article Chemistry, Multidisciplinary

Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles

Ayumi Harada et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

添加到收藏夹

Review Multidisciplinary Sciences

Solar Synthesis: Prospects in Visible Light Photocatalysis

Danielle M. Schultz et al.

SCIENCE (2014)

添加到收藏夹

Article Chemistry, Organic

Regio- and Enantiospecific Rhodium-Catalyzed Allylic Substitution with an Acyl Anion Equivalent

P. Andrew Evans et al.

ORGANIC LETTERS (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Z-Selective Copper-Catalyzed Asymmetric Allylic Alkylation with Grignard Reagents

Massimo Giannerini et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

添加到收藏夹

Review Chemistry, Multidisciplinary

Visible light photoredox catalysis: applications in organic synthesis

Jagan M. R. Narayanam et al.

CHEMICAL SOCIETY REVIEWS (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

Photochemically Promoted Transition Metal-Free Cross-Coupling of Acylsilanes with Organoboronic Esters

Kazuta Ito et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

添加到收藏夹

Article Chemistry, Multidisciplinary

Enantioselective Alkenylation via Nickel-Catalyzed Cross-Coupling with Organozirconium Reagents

Sha Lou et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

添加到收藏夹

Review Chemistry, Multidisciplinary

Catalytic asymmetric conjugate addition and allylic alkylation with Grignard reagents

Syuzanna R. Harutyunyan et al.

CHEMICAL REVIEWS (2008)

添加到收藏夹

Review Chemistry, Multidisciplinary

Enantioselective copper-catalyzed conjugate addition and allylic substitution reactions

A. Alexakis et al.

CHEMICAL REVIEWS (2008)

添加到收藏夹

Review Chemistry, Organic

Copper-catalyzed asymmetric allylic alkylation

Caroline A. Falciola et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2008)

添加到收藏夹

Article Chemistry, Multidisciplinary

Recent progress in asymmetric allylic substitutions catalyzed by chiral copper complexes

H Yorimitsu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2005)

添加到收藏夹

Review Chemistry, Multidisciplinary

Photoactive mono- and polynuclear Cu(I)-phenanthrolines. A viable alternative to Ru(II)-polypyridines?

N Armaroli

CHEMICAL SOCIETY REVIEWS (2001)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Photochemistry induced by metal-to-ligand charge transfer excitation

A Vogler et al.

COORDINATION CHEMISTRY REVIEWS (2000)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.